no Mesity I oxide, (CH3)₂ C = CHRO CH 3 shows 2 bange at 230mm [12600) and 32-tom. But its isomer does not show any bands above 210nm. Explain

Q: The d-electron count of the transition metal center for [(7-CSHS)Ir(CO)2(CH3)* and [Rh(PPH3)3Cl],…

A: Calculate metal electrons in organometallic compound [η5-C5H5IrCO2CH3]+ and  RhPPh33Cl Given: Atomic…

Q: Metal ligand bonds tend to be weak and often are observed to vibrate below 600cm-1. Can you foresee…

A: Metal ligand bonds tend to be weak and often are observed to vibrate below 600cm-1.

Q: mixture of Me₂NC 1₂PPh₂ and and KSCN with K₂[Pd] gives a square planar complex A. Identify the…

A: s and p both form pie bonding with complex and pie bonding capacity of sulphur is greater…

Q: Three peaks are observed at 9000, 14500, 24500 cm-1 in the [Ni(H2O)6]2+ uv-vis spectrum. What is the…

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Q: (a) Give the formal oxidation number and the d-electron count of the transition element and the…

A: In metal complexes, the central transition metal is often surrounded by ligands, which are neutral…

Q: 1. (a) Determine the valence electron counts on the transition metals. Find out the formal oxidation…

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Q: Fill in the blanks to name the coordination complex shown below. cis- -- ОН H2O,,. | 1OH он Fe H2O |…

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Q: Indicate the coordination geomerty, the metal oxidation state, the d-electron count, and the…

A: Coordination geometry = square planar Metal oxidation state = +2  (Fe = 26) d-electron count  = 6…

Q: Attached is the structure and nmr of [(+)Co(en)3]I3 * H2O . Please assign placement for the non…

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Q: In the octahedral field, dx2-v2 and d,2 are denoted as e, orbitals with the s-symmetry while dxy,…

A: In octahedral field, the molecular orbital diagram in different kind of ligand is different.…

Q: Consider the given Orgel diagram for d', d“, dº, and dº ions in octahedral and tetrahedral fields,…

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Q: 2. Predict the transition metal-containing products of the following reactions and label which type…

A: “Since you have posted a question with multiple sub-parts, we will solve the first three subparts…

Q: In which of the following cases all complexes are square planes? (27Co, 28Ni, 46Pd, 78Pt, 79Au)…

A: Coordination complexes  with coordination number 4 can be either tetrahedral or square planar.…

Q: (b) Predict the product and chemistry involved in the following reactions: (i) [Rh(CO)2C12] +CH3I…

A: Since you have asked a question with a multiple sub-parts, we will solve first three sub-parts for…

Q: what is the electron configuration of Mn in [MnO4]1+ b, what is the magnetic moment of Mn in [MnO4]…

A: The given compound is made up of one manganese and four oxygen atoms.Oxidation number of  oxygen (O)…

Q: 8. Which of the following arrangement is correct according to increasing stretching frequency? (A)…

A: Transition metal are those in which last electron enter the d subshell. Transition metals are placed…

Q: 15 (a) Predict the possible magnetic moments of Co(II) in square planar, tetrahedral and octahedral…

A: The magnetic moment of transition metal complexes depend on the type of ligand environment it is…

Q: formal oxidation number and the d-electron count

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Q: Find out the first row transition metals (M) for the following compounds (all of them obey 18e rule)…

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Q: What will happen to the C=C bond of the ligand and oxidation state of the metal centre upon…

A: This reaction is the oxidation reaction in organometallic compound.

Q: Designate the following complexes X,Y,Z as inert or labile: X= [AI(H,O),]³+ ; Y=V(H,O),J?* ;…

A: X = [Al(H2O)6]2+ Main group elements are generally labile.

Q: A complex of metal M"+ has the following electronic distribution ind orbitals, 1l E The neutral M…

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Q: T1,O pyridine BH в A C Cul, Pd(PPh,), Br Br Pd(PPh,) NaOEt Pd(OAC), PPh,. NEt, E D

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Q: (c) The ligands to meta! charge transfer bands (LMCT) increases in the series Col <CoBr <COCI…

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Q: What is the concentration of free Co3+ in 1.2642e-5 M Co(NO3)3 and 1.3948 M NH3? Co3+ + 6 NH3 →…

A: Concentration of Co(NO3)3 = 1.2642 x 10-5 M  Concentration of NH3 = 1.3948 M  Kf for the reaction =…

Q: Construct a mode | of [Cr (C2 O4 Make sure are linked to donor atoms to indicate how the atorms…

A: The IUPAC name of this compound is Tris Oxalato chromium. It is a coordination compound. there is a…

Q: Which of the following compounds follow the effective atomic number rule, and which do not?(27Co,…

A: Effective atomic number rule is defined as the total number of electrons present around the central…

Q: draw the orbital overlap between transition metal d-orbitals and an oxo p-orbitals to form a triple…

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Q: Find out the first row transition metals (M) for the following compounds (all of them obey 18e rule)…

A: The 18 e- rule is used to predict the formula for stable metal complex. Also it can help in…

Q: Characterize each of t Following CooXDivation comprends M₂₂ [Cr CH₂)₂ (CN)+] [M(NH3)3 Brolls…

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Q: Select the best choice in each of the following and briefly justify the reason for your selection.…

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Q: Chapter Home Pes) Calcolate the eauiü briem (castant for te dispro portionaticn of ne T ron (II) :on…

A: The reactions given are, 1) Fe2+ (aq) + 2 e- → Fe (s)                      Eo = -0.44 V 2) Fe3+ (aq)…

Q: (b) [Zn(II)(H2O)6]?* can undergo successive reactions with phen ligands: [Zn(II)(H2O)«(phen)]²* +…

A: Phen ligand (b) as number of phen ligand increases stability (logKf) decreases due to increase…

Q: Draw structures, crystal field diagrams, calculate expected spin only magnetic moment for the…

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Q: (a) UV/Vis spectra of [Mn(H2O)]*, [Co(H2O)%]**, and [CoCla are dominated by transitions that have…

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Q: 18-electron rule

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Q: Explain the d-d transitions for [Ti(H2O)6]3+

A: Solution: a)for [Ti(H2O)6]3+ complex. Here first we habe to find how many electron are there in d…

Q: 1. (a) Determine the valence electron counts on the transition metals. Find out the formal oxidation…

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Q: itions

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Q: When the anion of the amino acid glycine, H2NCH2CO2-(gly-), reacts with cobalt(III) oxide, both the…

A: When the anion of the amino acid glycine, H2NCH2CO2-(gly-), reacts with cobalt(III) oxide, both the…

Q: NHTS Co(D-Porph) (2 mol%) OCH Cs,COs CH,OH; 40 °C; 24 h ÓCH, OCH trans cis

A: From the tosylated hydrazone derivatives carbene can be generated feasibly through nitrogen…

Q: Predict the nature, including the correct special isomerisation (i.e. cis/trans) when necessary, of…

A: A question based on trans effect, which is to be accomplished.

Q: 13. Which of following complexes is paramagnetic? 3+ (B) [FeF«]* (C) [Zn(NH3)4]2+ (D) [Co(H;O)6] 4-…

A: (13) Paramagnetic objects are attracted to magnetic forces. Many flexible metal structures have…

Q: Consider the reaction scheme below. Me Me- 0 1970 butto Holament 9 COMI20 OH (ii) Explain briefly…

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Stereochemistry and Isomerism

Stereochemistry deals with the three-dimensional structure and properties of molecules. It explains the arrangement of atoms and their manipulation within a molecule in a 3D structure. Stereochemistry can be dealt with all types of molecules. Based on the stereochemistry of a molecule, the physical and chemical properties of the molecules vary.