NH2 Br CH₂ 0= 11 COH Br Br GIVE Present a Synthesis method for Synthesizing the given product by reacting with 3-methylaniline as a Starting material
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- Reaction of p-cresol with two equivalents of 2-methylprop-1-ene affordsBHT, a preservative with molecular formula C15H24O. BHT gives thefollowing 1H NMR spectral data: 1.4 (singlet, 18 H), 2.27 (singlet, 3 H), 5.0(singlet, 1 H), and 7.0 (singlet, 2 H) ppm. What is the structure of BHT?Draw a stepwise mechanism illustrating how it is formed.Identify the major prouct of the folowing sololvsi reaction of 3bromo-1-methyiycopentene with methanol, Br CH,OH toFor each compound, give the product(s) expected from (1) HgSO4>H2SO4@catalyzedhydration and (2) hydroboration–oxidation.(a) hex-1-yne
- Devise at least three different methods to prepare N-methylbenzylamine (PhCH2NHCH3) from benzene, any one-carbon organic compounds, and any required reagents.The following presented reaction scheme lead to the synthesis of which major product from benzene assuming separation of products is possible? 1 NaOH CI. Product Product HSO 2 H,0 FeCl OA Meta-Chlorophenol U& para-ChloroSulfenic acid 6C Para-Chlorophenol 0O Mela chioroanilineA molecule of propanone reacts with an cyclohexylethanone in presence of aq. NaOH to combine together, and the resulting product is boiled to produce another product, (i) CH3 -NH2 НО H;CO
- Sharpless epoxidation of allylic alcohol X forms compound Y. Treatmentof Y with NaOH and C6H5SH in an alcohol–water mixture forms Z. Identifythe structure of Y and draw a mechanism for the conversion of Y to Z.Account for the stereochemistry of the stereogenic centers in Z. Z hasbeen used as an intermediate in the synthesis of chiral carbohydrates.Devise a synthesis of the ketone hexan-3-one, CH3CH2COCH2CH2CH3, from CH3CH2Br as the only organic starting material; that is, all the carbon atoms in hexan-3-one must come from CH3CH2Br. You may use any other neededreagents.Which of the following reactions will synthesize phenol from benzene? 1) HNO3 + H2SO4; 2) Fe, HCl; 3) NaNO2, HCl, 0-10 oC; 4) warm H2SO4 and H2O 1) HNO3 + H2SO4; 2) Fe, HCl; 3) NaNO2, HCl, 0-10 oC; 4) CuCN; 5) dilute acid and heat 1) Acetyl chloride & AlCl3; 2) bleach 1) Ph-N2+ + KI; 2) BrMgCH=CH2 in ether, followed by H3O+; 3) warm, conc'd KMnO4 1) Cl-CH(CH3)-CH2CH2CH3 + FeBr3; 2) hot, conc'd KMnO4
- For each compound, give the product(s) expected from (1) HgSO4>H2SO4@catalyzedhydration and (2) hydroboration–oxidation.(a) hex-1-yne (b) hex-2-yneWhen cis-2-decalone is dissolved in ether containing a trace of HCl, an equilibrium is established with trans-2-decalone. The latter ketone predominates in the equilibrium mixture. Propose a mechanism for this isomerization and account for the fact that the trans isomer predominates at equilibrium.The following equation shows the reaction of trans-2,3-diphenyloxirane with hydrogen chloride in benzene to form 2-chloro-1,2-diphenylethanol. (a) How many stereoisomers are possible for 2-chloro-1,2-diphenylethanol? (b) Given that opening of the epoxide ring in this reaction is stereoselective, predict which of the possible stereoisomers of 2-chloro-1,2-diphenylethanol is/are formed in the reaction.