NaOH, H20PhcoPhCOheatmixtureCAII. Two of the following mechanisms are wrong, indicate which ones. List your selection in alphabetical order fromleft to right. EaunA) HÖ:_HCH,CH,CPh- CH,CH,CPnli st y our choices inal phabeti cal orderexam ple if A and Bthen 6. A and 7. Band not 6. B and 7. AB) PhCCH2CH2 0:6.7.C) CH,C-ÖCCH;CH,Cči::Cl :D) CH,CÖCH, ÖHCH,CÖCH,

A. β hydrogens are less acidic than α protons. Therefore base will pick the hydrogen from α carbon.…

NaOH, H20 PhCO- PHCO + heat C A II. Two of the following mechanisms are wrong, indicate which ones. List your selection in alphabetical order from left to right. Eaun A) HÖ: - CH,CH,CPh H- li st y our choices in al phabeti cal order example if A and B then 6. A and 7. B and not 6. B and 7. A B) PhCCH, CH2 0: PhCH,CH0: 6. 7. C) CH3C-OCCH, CH,cči: + ;öcCH; .. :Cl : D) CH,CÖCH, GÖH CH,CÖCH,

NaOH, H20 PhCO- PHCO + heat C A II. Two of the following mechanisms are wrong, indicate which ones. List your selection in alphabetical order from left to right. Eaun A) HÖ: - CH,CH,CPh H- li st y our choices in al phabeti cal order example if A and B then 6. A and 7. B and not 6. B and 7. A B) PhCCH, CH2 0: PhCH,CH0: 6. 7. C) CH3C-OCCH, CH,cči: + ;öcCH; .. :Cl : D) CH,CÖCH, GÖH CH,CÖCH,

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter30: Orbitals And Organic Chemistry: Pericyclic Reactions

Section30.7: Sigmatropic Rearrangements

Problem 7P

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