N2O5 is used as a source of NO2 in chemical reactions. The compound decomposes in a first order reaction. If the initial concentration of N2O5 = 0.400 M, and the concentration is 0.025 M after 120 seconds, what is the rate constant k of the reaction? a. 7.50 s-1 b. 333 s-1 c. 2.77 s-1 d. 2.31 x 102s1 e. 5.21 x 104s
N2O5 is used as a source of NO2 in chemical reactions. The compound decomposes in a first order reaction. If the initial concentration of N2O5 = 0.400 M, and the concentration is 0.025 M after 120 seconds, what is the rate constant k of the reaction? a. 7.50 s-1 b. 333 s-1 c. 2.77 s-1 d. 2.31 x 102s1 e. 5.21 x 104s
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![**Chemical Reaction Kinetics Example Problem**
*Nitrogen Pentoxide Decomposition Rate Constant Calculation*
**Problem:**
N₂O₅ is used as a source of NO₂ in chemical reactions. The compound decomposes in a first-order reaction. If the initial concentration of N₂O₅ is 0.400 M, and the concentration is 0.025 M after 120 seconds, what is the rate constant \( k \) of the reaction?
**Options:**
a. 7.50 s\(^{-1}\)
b. 333 s\(^{-1}\)
c. 2.77 s\(^{-1}\)
d. 2.31 × 10\(^{-2}\) s\(^{-1}\)
e. 5.21 × 10\(^{-4}\) s\(^{-1}\)
**Solution Strategy:**
To find the reaction rate constant \( k \) for a first-order reaction, use the first-order kinetics formula:
\[ \ln([A]_t) = \ln([A]_0) - kt \]
Where:
- \([A]_t\) is the concentration of N₂O₅ at time \( t \)
- \([A]_0\) is the initial concentration of N₂O₅
- \( t \) is the time elapsed
- \( k \) is the rate constant to be determined
Given:
- \([A]_0 = 0.400 \, M\)
- \([A]_t = 0.025 \, M\)
- \( t = 120 \, \text{s}\)
Follow these steps to solve for \( k \):
1. Substitute the given concentrations and time into the first-order kinetics formula.
2. Rearrange and solve for \( k \).
This example helps illustrate the application of first-order kinetics principles in determining the rate constant of a decomposition reaction.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fc31825ca-e532-4346-8c67-c6f0bc8ad95c%2F00718f83-b69f-4987-bfc5-e1fb8f497569%2F9m4a8k_processed.jpeg&w=3840&q=75)
Transcribed Image Text:**Chemical Reaction Kinetics Example Problem**
*Nitrogen Pentoxide Decomposition Rate Constant Calculation*
**Problem:**
N₂O₅ is used as a source of NO₂ in chemical reactions. The compound decomposes in a first-order reaction. If the initial concentration of N₂O₅ is 0.400 M, and the concentration is 0.025 M after 120 seconds, what is the rate constant \( k \) of the reaction?
**Options:**
a. 7.50 s\(^{-1}\)
b. 333 s\(^{-1}\)
c. 2.77 s\(^{-1}\)
d. 2.31 × 10\(^{-2}\) s\(^{-1}\)
e. 5.21 × 10\(^{-4}\) s\(^{-1}\)
**Solution Strategy:**
To find the reaction rate constant \( k \) for a first-order reaction, use the first-order kinetics formula:
\[ \ln([A]_t) = \ln([A]_0) - kt \]
Where:
- \([A]_t\) is the concentration of N₂O₅ at time \( t \)
- \([A]_0\) is the initial concentration of N₂O₅
- \( t \) is the time elapsed
- \( k \) is the rate constant to be determined
Given:
- \([A]_0 = 0.400 \, M\)
- \([A]_t = 0.025 \, M\)
- \( t = 120 \, \text{s}\)
Follow these steps to solve for \( k \):
1. Substitute the given concentrations and time into the first-order kinetics formula.
2. Rearrange and solve for \( k \).
This example helps illustrate the application of first-order kinetics principles in determining the rate constant of a decomposition reaction.
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