Molecular ekacagine combines with ethylene to form diekaethylene (C2H2Ec2) according to the reaction below: Examine the bond energies in Table 9.3 of your textbook. Shuri’s undergrads measured the new bond enthalpies: C-Ec bond energy is 220 kJ/mol and the Ec-Ec bond energy is 120 kJ/mol. Calculate the enthalpy change when 1 mol of ethylene is converted to diekaethylene. Calculate the enthalpy change when 9.00 x 103 kg of ethylene is converted to diekaethylene.
Types of Chemical Bonds
The attractive force which has the ability of holding various constituent elements like atoms, ions, molecules, etc. together in different chemical species is termed as a chemical bond. Chemical compounds are dependent on the strength of chemical bonds between its constituents. Stronger the chemical bond, more will be the stability in the chemical compounds. Hence, it can be said that bonding defines the stability of chemical compounds.
Polarizability In Organic Chemistry
Polarizability refers to the ability of an atom/molecule to distort the electron cloud of neighboring species towards itself and the process of distortion of electron cloud is known as polarization.
Coordinate Covalent Bonds
A coordinate covalent bond is also known as a dative bond, which is a type of covalent bond. It is formed between two atoms, where the two electrons required to form the bond come from the same atom resulting in a semi-polar bond. The study of coordinate covalent bond or dative bond is important to know about the special type of bonding that leads to different properties. Since covalent compounds are non-polar whereas coordinate bonds results always in polar compounds due to charge separation.
Bond Energies (kJ/mol) | |||||
---|---|---|---|---|---|
Bond | Bond Energy | Bond | Bond Energy | Bond | Bond Energy |
H–H | 436 | C–S | 260 | F–Cl | 255 |
H–C | 415 | C–Cl | 330 | F–Br | 235 |
H–N | 390 | C–Br | 275 | Si–Si | 230 |
H–O | 464 | C–I | 240 | Si–P | 215 |
H–F | 569 | N–N | 160 | Si–S | 225 |
H–Si | 395 | N=NN=N | 418 | Si–Cl | 359 |
H–P | 320 | N≡NN≡N | 946 | Si–Br | 290 |
H–S | 340 | N–O | 200 | Si–I | 215 |
H–Cl | 432 | N–F | 270 | P–P | 215 |
H–Br | 370 | N–P | 210 | P–S | 230 |
H–I | 295 | N–Cl | 200 | P–Cl | 330 |
C–C | 345 | N–Br | 245 | P–Br | 270 |
C=CC=C | 611 | O–O | 140 | P–I | 215 |
C≡CC≡C | 837 | O=OO=O | 498 | S–S | 215 |
C–N | 290 | O–F | 160 | S–Cl | 250 |
C=NC=N | 615 | O–Si | 370 | S–Br | 215 |
C≡NC≡N | 891 | O–P | 350 | Cl–Cl | 243 |
C–O | 350 | O–Cl | 205 | Cl–Br | 220 |
C=OC=O | 741 | O–I | 200 | Cl–I | 210 |
C≡OC≡O | 1080 | F–F | 160 | Br–Br | 190 |
C–F | 439 | F–Si | 540 | Br–I | 180 |
C–Si | 360 | F–P | 489 | I–I | 150 |
C–P
|
265 | F–S | 285 |
- Molecular ekacagine combines with ethylene to form diekaethylene (C2H2Ec2) according to the reaction below:
- Examine the bond energies in Table 9.3 of your textbook. Shuri’s undergrads measured the new bond enthalpies: C-Ec bond energy is 220 kJ/mol and the Ec-Ec bond energy is 120 kJ/mol. Calculate the enthalpy change when 1 mol of ethylene is converted to diekaethylene.
- Calculate the enthalpy change when 9.00 x 103 kg of ethylene is converted to diekaethylene.
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