Methanol is used as a raw material in the manufacture of formaldehyde, acetic acid, methyl tertiary-butyl ether (MTBE), and several other important chemicals. It also has many other uses, including as a solvent, a disinfectant, and a clean-burning fuel. One of the ways it can be synthesized is by reacting carbon dioxide and hydrogen gas. The by-product of the reaction is water. The fresh feed to a methanol synthesis process contains hydrogen gas, carbon dioxide, and 0.4 mole % inerts. The reactor effluent passes to a condenser that removes essentially all of the methanol and water formed and none of the reactants or inerts. The latter substances are recycled to the reactor. To avoid buildup of the inerts in the system, a purge stream is withdrawn from the recycle. The feed to the reactor contains 28.0 mole % carbon dioxide, 70.0 mole % hydrogen, and 2.00 mole % inerts. The single-pass conversion of hydrogen is 57.0 %. Generate a process data sheet (tabular) showing molar flow rates and molar compositions of the following streams for every 500 kmol/hr of methanol produced. Use the extent of reaction balances. • Fresh feed • Gross feed to the reactor • Recycle stream • Purge stream • Product stream Fill out the process data sheet below: Composition (mol %) Stream Molar flowrate (kmol/hr) CO2 H2 CH3OH H2O Inert Fresh [ Select ] [ Select] [ Select ] 0.4 feed Gross [ Select ] 28 70 2 feed Recycle ( Select ] [ Select ] Purge [ Select ] [ Select ] Product [ Select] [ Select ]

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
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Material Balance

Methanol is used as a raw material in the manufacture of formaldehyde, acetic acid, methyl tertiary-butyl ether (MTBE), and several other important chemicals. It also has many other
uses, including as a solvent, a disinfectant, and a clean-burning fuel. One of the ways it can be synthesized is by reacting carbon dioxide and hydrogen gas. The by-product of the
reaction is water. The fresh feed to a methanol synthesis process contains hydrogen gas, carbon dioxide, and 0.4 mole % inerts. The reactor effluent passes to a condenser that
removes essentially all of the methanol and water formed and none of the reactants or inerts. The latter substances are recycled to the reactor. To avoid buildup of the inerts in the
system, a purge stream is withdrawn from the recycle. The feed to the reactor contains 28.0 mole % carbon dioxide, 70.0 mole % hydrogen, and 2.00 mole % inerts. The single-pass
conversion of hydrogen is 57.0 %. Generate a process data sheet (tabular) showing molar flow rates and molar compositions of the following streams for every 500 kmol/hr of
methanol produced. Use the extent of reaction balances.
• Fresh feed
• Gross feed to the reactor
• Recycle stream
• Purge stream
• Product stream
Fill out the process data sheet below:
Composition (mol %)
Stream Molar flowrate (kmol/hr)
CO2
H2
CH3OH
H20 Inert
Fresh
[ Select ]
[ Select ]
[ Select ]
0.4
feed
Gross
[ Select ]
28
70
2
feed
Recycle [ Select]
[ Select ]
Purge
[ Select ]
[ Select ]
Product
[ Select ]
[ Select ]
Transcribed Image Text:Methanol is used as a raw material in the manufacture of formaldehyde, acetic acid, methyl tertiary-butyl ether (MTBE), and several other important chemicals. It also has many other uses, including as a solvent, a disinfectant, and a clean-burning fuel. One of the ways it can be synthesized is by reacting carbon dioxide and hydrogen gas. The by-product of the reaction is water. The fresh feed to a methanol synthesis process contains hydrogen gas, carbon dioxide, and 0.4 mole % inerts. The reactor effluent passes to a condenser that removes essentially all of the methanol and water formed and none of the reactants or inerts. The latter substances are recycled to the reactor. To avoid buildup of the inerts in the system, a purge stream is withdrawn from the recycle. The feed to the reactor contains 28.0 mole % carbon dioxide, 70.0 mole % hydrogen, and 2.00 mole % inerts. The single-pass conversion of hydrogen is 57.0 %. Generate a process data sheet (tabular) showing molar flow rates and molar compositions of the following streams for every 500 kmol/hr of methanol produced. Use the extent of reaction balances. • Fresh feed • Gross feed to the reactor • Recycle stream • Purge stream • Product stream Fill out the process data sheet below: Composition (mol %) Stream Molar flowrate (kmol/hr) CO2 H2 CH3OH H20 Inert Fresh [ Select ] [ Select ] [ Select ] 0.4 feed Gross [ Select ] 28 70 2 feed Recycle [ Select] [ Select ] Purge [ Select ] [ Select ] Product [ Select ] [ Select ]
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