Metallic Titanium and its alloys (especially those with aluminum and vanadium) combine the advantages of high strength and light weight and are therefore used widely in the aerospace industry for the bodies and engines of airplanes. The major natural source for titanium is the ore rutile, which contains titanium dioxide (TiO₂). a. An intermediate in the preparation of elemental titanium from TiO₂2 is a volatile chloride of titanium (boiling point = 136°C) that contains 25.24% titanium by mass. Determine the empirical formula of this compound. b. At 136°C and atmospheric pressure, the density of this gaseous metal chloride is 5.65 g/L. Determine the molecular formula of this compound. (Hint: determine its molecular mass first)

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Metallic Titanium and its alloys (especially those with aluminum and vanadium) combine the advantages
of high strength and light weight and are therefore used widely in the aerospace industry for the bodies
and engines of airplanes. The major natural source for titanium is the ore rutile, which contains titanium
dioxide (TiO₂).
a.
An intermediate in the preparation of elemental titanium from TiO2 is a volatile chloride of
titanium (boiling point = 136°C) that contains 25.24% titanium by mass. Determine the empirical
formula of this compound.
b. At 136°C and atmospheric pressure, the density of this gaseous metal chloride is 5.65 g/L.
Determine the molecular formula of this compound. (Hint: determine its molecular mass first)
Transcribed Image Text:Metallic Titanium and its alloys (especially those with aluminum and vanadium) combine the advantages of high strength and light weight and are therefore used widely in the aerospace industry for the bodies and engines of airplanes. The major natural source for titanium is the ore rutile, which contains titanium dioxide (TiO₂). a. An intermediate in the preparation of elemental titanium from TiO2 is a volatile chloride of titanium (boiling point = 136°C) that contains 25.24% titanium by mass. Determine the empirical formula of this compound. b. At 136°C and atmospheric pressure, the density of this gaseous metal chloride is 5.65 g/L. Determine the molecular formula of this compound. (Hint: determine its molecular mass first)
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The titanium chloride dealt with in parts (a) and (b) is produced by the reaction of chlorine with a hot mixture of titanium dioxide and coke (carbon), with carbon dioxide generated as a by-product. Write a balanced chemical equation for this reaction. 

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