Metal sulfides are prepared by bubbling hydrogen sulfide gas, H₂S, through an aqueous solution containing the metal ion, and then adjusting the pH. When the solution is saturated with H₂S, which occurs when [H₂S] = 0.100 M, the equilibrium shown is established. H,S(aq) +2H,O(I)=S2-(aq) +2H,O*(aq) An aqueous solution containing 0.0382 M Pb²+ and 0.0382 M Ag+ is saturated with H₂S. Above what concentration of S²- w PbS precipitate? The Ksp of PbS is 8.9 x 10-2⁹. [s2-] = [s²-] = Above what concentration of S²- will Ag₂S precipitate? The Ksp of Ag₂S is 3.3 × 10-50. Keq neither species both PbS and Ag₂S = 1.1 x 10-20 If the pH of the solution is adjusted to 3.56, which species will precipitate from the saturated H₂S solution? Phs M M

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Chapter1: Chemical Foundations
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Metal sulfides are prepared by bubbling hydrogen sulfide gas, H₂S, through an aqueous solution containing the metal ion, and
then adjusting the pH. When the solution is saturated with H₂S, which occurs when [H₂S] = 0.100 M, the equilibrium shown
is established.
H₂S(aq) + 2 H₂O(1) S²-(aq) + 2H₂O+ (aq)
An aqueous solution containing 0.0382 M Pb²+ and 0.0382 M Ag+ is saturated with H₂S. Above what concentration of S²- will
PbS precipitate? The Ksp of PbS is 8.9 × 10-2⁹.
[S²-] =
[s²] =
Above what concentration of S²- will Ag₂S precipitate? The Ksp of Ag₂S is 3.3 x 10-50.
O neither species
Keq =
If the pH of the solution is adjusted to 3.56, which species will precipitate from the saturated H₂S solution?
both PbS and Ag₂S
= 1.1 x 10-20
Phs
M
M
Transcribed Image Text:Metal sulfides are prepared by bubbling hydrogen sulfide gas, H₂S, through an aqueous solution containing the metal ion, and then adjusting the pH. When the solution is saturated with H₂S, which occurs when [H₂S] = 0.100 M, the equilibrium shown is established. H₂S(aq) + 2 H₂O(1) S²-(aq) + 2H₂O+ (aq) An aqueous solution containing 0.0382 M Pb²+ and 0.0382 M Ag+ is saturated with H₂S. Above what concentration of S²- will PbS precipitate? The Ksp of PbS is 8.9 × 10-2⁹. [S²-] = [s²] = Above what concentration of S²- will Ag₂S precipitate? The Ksp of Ag₂S is 3.3 x 10-50. O neither species Keq = If the pH of the solution is adjusted to 3.56, which species will precipitate from the saturated H₂S solution? both PbS and Ag₂S = 1.1 x 10-20 Phs M M
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