Metal corrosion by aqueous acid is a favorable process under many normal conditions and one of the many problems caused by acid rain. Use the following reaction and tabulated values to calculate ∆H and ∆S for the following reaction between metallic iron and free acid generated by species such as H2SO4. What is the overall favorability of the reaction (∆G) assuming STP? Fe (s) + 2H(aq)--> Fe(aq)+ H2(g) Species ∆Ηfo (kJ/mol) S (J/mol*K) Fe 0 27.28 H2 0 130.68 Fe2+ -89.1 -137.7 H+ 0 0

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Metal corrosion by aqueous acid is a favorable process under many normal conditions and one of the many problems caused by acid rain. Use the following reaction and tabulated values to calculate ∆H and ∆S for the following reaction between metallic iron and free acid generated by species such as H2SO4. What is the overall favorability of the reaction (∆G) assuming STP?

Fe (s) + 2H(aq)--> Fe(aq)+ H2(g)

Species

∆Ηfo (kJ/mol)

S (J/mol*K)

Fe

0

27.28

H2

0

130.68

Fe2+

-89.1

-137.7

H+

0

0

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