MC1. Grignard reagent and organolithium reagents can be prepared in presence of acidicfunctional groups.MC2. Gilman reagents react with formaldehyde and gives alcohol.MC3. An SN2 attack on the chiral center would result in inversion of stereochemistry.MC4. Acetal cannot be formed in base as the -OH group is a bad leaving group.MC5. Carbon dioxide can readily react with Gilman reagent to form carboxylic acid.MC6. Alkynes anion are powerful nucleophiles that react with epoxides, aldehyde and ketones.MC7. Simple phosphonium yilde forms the Z product which is the thermodynamic product.MC8. When the reaction is under kinetic control the ratio of the products formed is determined bythe relative energies of the transition states.MC9. A significant concentration of strong acids and strong bases cannot co-exist in the samereaction.MC10. The driving force for the Wittig reaction is the formation of a strong carbon-carbon doublebond.MC11. A baby-shark trap can be used to remove alcohol or water from the reaction mixture.MC12. Phosphonium ylide can be formed from a 3º Haloalkane.MC13. Consider the following reversible dehydration reaction. Adding water to the reaction wouldform the alkene.OHCat H₂SO4OCH3 H₂OMC14. Consider the following reversible Hydrolysis of Ester reaction. Adding water to thereaction would form the ester.H₂OCat H₂SO4OH CH3OH

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MC1. Grignard reagent and organolithium reagents can be prepared in presence of acidic functional groups. MC2. Gilman reagents react with formaldehyde and gives alcohol. MC3. An S№2 attack on the chiral center would result in inversion of stereochemistry.

MC1. Grignard reagent and organolithium reagents can be prepared in presence of acidic functional groups. MC2. Gilman reagents react with formaldehyde and gives alcohol. MC3. An S№2 attack on the chiral center would result in inversion of stereochemistry.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Concept explainers

Alkanes and Cycloalkanes

Alkanes are saturated organic compounds which are made up of C and H atoms. Alkanes have the general formula of CnH2n+2. Alkane contains sp3 hybridized carbon atoms with four sigmas (σ) bonds & every hydrogen atom is connected with one of the carbon atoms. The size of the alkane could be determined by the number of carbon atoms located in it.

Question

100%

MC1. Grignard reagent and organolithium reagents can be prepared in presence of acidic
functional groups.
MC2. Gilman reagents react with formaldehyde and gives alcohol.
MC3. An SN2 attack on the chiral center would result in inversion of stereochemistry.
MC4. Acetal cannot be formed in base as the -OH group is a bad leaving group.
MC5. Carbon dioxide can readily react with Gilman reagent to form carboxylic acid.
MC6. Alkynes anion are powerful nucleophiles that react with epoxides, aldehyde and ketones.
MC7. Simple phosphonium yilde forms the Z product which is the thermodynamic product.
MC8. When the reaction is under kinetic control the ratio of the products formed is determined by
the relative energies of the transition states.
MC9. A significant concentration of strong acids and strong bases cannot co-exist in the same
reaction.
MC10. The driving force for the Wittig reaction is the formation of a strong carbon-carbon double
bond.
MC11. A baby-shark trap can be used to remove alcohol or water from the reaction mixture.
MC12. Phosphonium ylide can be formed from a 3º Haloalkane.
MC13. Consider the following reversible dehydration reaction. Adding water to the reaction would
form the alkene.
OH
Cat H₂SO4
OCH3 H₂O
MC14. Consider the following reversible Hydrolysis of Ester reaction. Adding water to the
reaction would form the ester.
H₂O
Cat H₂SO4
OH CH3OH

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