Matter can change from one physical state (phase) to another without any change in chemical identity. Each phase change (PC) is characterized by a ApcH (enthalpy) value, and a ApcS (entropy) value. For each phase change,

Matter can change from one physical state (phase) to another without any change in chemical identity. Each phase change (PC) is characterized by a ApcH (enthalpy) value, and a ApcS (entropy) value. For each phase change,

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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A student dissolves 11.9 g of sodium chloride (NaCl)in 250. g of water in a well-insulated open cup. He then observes the temperature of the water fall from 23.0 °C to 22.0 °C over the course of 6.9 minutes. Use this data, and any information you need from the ALEKS Data resource, to answer the questions below about this reaction: + NaCl (s) - Na" (aq) + Ci¯ (aq) You can make any reasonable assumptions about the physical properties of the solution. Be sure answers you calculate using measured data are rounded to the correct number of significant digits. Note for advanced students: it's possible the student did not do the experiment carefully, and the values you calculate may not be the same as the known and published values for this reaction. exothermic x10 Is this reaction exothermic, endothermic, or neither? endothermic neither If you said the reaction was exothermic or endothermic, calculate the amount of heat that was released or absorbed by the reaction in this case. kJ kJ…
In the following experiment, solid CaCl2 (M = 110.98 g/mol) is dissolved in water:CaCl2(s) → Ca2+(aq) + 2Cl-(aq) ΔsolnH = ? kJ mol−1A 4.00 g sample of CaCl2 is added to a coffee-cup calorimeter containing 125 g of H2O. The initial temperature of water in the calorimeter is 22.0°C and the final temperature is 27.5°C. What is the enthalpy change for the dissolution reaction (ΔsolnH) in kJ per mole of CaCl2? Assume the specific heat capacity of the solution is the same as water (Cs=4.18 J g-1 °C-1) and that no heat is lost to the calorimeter.
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Calculate ΔHrxn for the reaction: 7 C (s) + 8 H2 (g) → C7H16 (g) The following reactions and associated ΔHrxn values are may likely be helpful to you: Reaction A: C7H16(g) + 11 O2 (g) → 7 CO2 (g) + 8 H2O (g) ΔHrxn = -4817 kJ Reaction B: C (s) + O2 (g) → CO2 (g) ΔHrxn = -393.5 kJ Reaction C: 2 H2 (g) + O2 (g) → 2 H2O (g) ΔHrxn = -483.6 kJ
A particular container holds 3.77 mol of neon gas. The volume of this container can be altered by sliding a piston in or out. The volume is changed from 8.60 L to 12.20 L while at the same time the temperature is changed from 303 K to 345 K. The molar heat capacity, Cym, for neon is 12.47 J/(mol · K). Assume that this value will not change over the given temperature range. What is the change in entropy for the gas? AS = J/K TOOLS x10 MacBook Pro
A 1.22 g sample of acetic acid (HC2H3O2) was burned in excess oxygen in a bomb calorimeter. The calorimeter, which alone had a heat capacity of 2.67 kJ/oC, contained 7 g of water. The temperature of the calorimeter and its contents increased from 23.47oC to 27.95oC. What is ΔH (in kJ) for the combustion per 1.00 mol of acetic acid? MW of acetic acid is 60 g/mol. (Round off the final answer to ONE decimal place. Do not include the unit.)
PLEASE SHOW YOUR WORK (THIS IS NOT A GRADED ASSIGNMENT)
Calculate ΔHo for the process ½ N2(g) + ½ O2(g) → NO(g) from the following information N2(g) + 2 O2(g) → 2 NO2(g) ΔHo = -105.8 kJ/mol 2 NO(g) + O2 → 2 NO2(g) ΔHo = -216.7 kJ/mol
A student dissolves 13.8 g of ammonium chloride (NH4Cl) in 250. g of water in a well-insulated open cup. She then observes the temperature of the water from 21.0 °C to 17.3 °C over the course of 6.3 minutes. Use this data, and any information you need from the ALEKS Data resource, to answer the questions below about this reaction: NH₂Cl(s) → NH(aq) + Cl¯ (aq) You can make any reasonable assumptions about the physical properties of the solution. Be sure answers you calculate using measured data are rounded to t correct number of significant digits. Note for advanced students: it's possible the student did not do the experiment carefully, and the values you calculate may not be the same as the known and published values for this reaction. Is this reaction exothermic, endothermic, or neither? If you said the reaction was exothermic or endothermic, calculate the amount of heat that was released or absorbed by the reaction in this case. Calculate the reaction enthalpy AH per mole of NH Cl.…
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Energy in the amount of 5.0 J is added to 0.50 g pieces of aluminum, copper, and magnesium that are initially kept at 22 °C. The molar heat capacities of these metals are 24.3 J/(mol·°C), 24.5 J/(mol·°C), and 24.9 J/(mol·°C), respectively. Which piece of metal will have the highest temperature and what is that temperature?
A student dissolves 10.7 g of lithium chloride (LiCl)in 300. g of water in a well-insulated open cup. She then observes the temperature of the water rise from 22.0 °C to 28.4 °C over the course of 3.6 minutes. Use this data, and any information you need from the ALEKS Data resource, to answer the questions below about this reaction: LiCl (s) Lit (aq) + Cl(aq) You can make any reasonable assumptions about the physical properties of the solution. Be sure answers you calculate using measured data are rounded to 2 significant digits. Note for advanced students: it's possible the student did not do the experiment carefully, and the values you calculate may not be the same as the known and published values for this reaction. Is this reaction exothermic, endothermic, or neither? If you said the reaction was exothermic or endothermic, calculate the amount of heat that was released or absorbed by the reaction in this case. Calculate the reaction enthalpy ΔΗ. per mole of LiCl. rxn 0 exothermic…