Match the appropriate octahedral crystal-field splitting diagram with the given spin state and metal ion. Metal ion and spin state high-spin Fe4+ low-spin Fe²+ Octahedral splitting diagram 1 12 12 12 1L 1 Answer Bank 14 1 1L 1L 1L 11 1L 1L 1 1L 1L 1

Q: Rank ligand type from weakest field to strongest field: - pi donor  - sigma only  - pi acceptor

A: Please have a look on the solution:

Q: None

A: Step 1:Tanabe-Sugano diagram provided shows the energy levels of the d-orbitals for a d3…

Q: Match the appropriate octahedral crystal-field splitting diagram with the given spin state and metal…

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Q: Which of the following ligands does not donate 6 electrons when coordinating to a transition metal…

A: A ligand is an ion or molecule that provides a central metal atom or ion with two electrons to…

Q: Which one of the following complexes is low-spin?   a) K4 [PdF6] b) K3[CoF6] c) CsK2[AgF6] d)…

A: Which one of the following complexes is low-spin?

Q: Which pair of transition metal ions would be expected to have the same magnetic moment? Group of…

A: Introduction :-  The magnetic moment of an atom or ion is calculated by the formula                μ…

Q: Which of the three selection rules (spin, orbital, Laporte) are broken by the following transition?…

A: Spin selection rule: During the transition of electrons spin multiplicity should not change (ΔS =…

Q: Three absorption bands were observed at 11200, 18350, 29000 cm-1 in the electronic spectrum of the…

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Q: Jahn-Teller distortions are often encountered with а. octahedral complexes of dº and high o spin d4…

A: Jahn teller distortion occurs in those complexes which has unpaired electron in t2g or eg orbital ie…

Q: Match the appropriate octahedral crystal-field splitting diagram with for the metal ion with the…

A: high spin complexes contain unpaired electrons low spin complexes tend to contain paired electrons

Q: In general, what is the correct correlation between ligand type and its trans-directing ability in…

A: Trans direction ability is the ability to of the ligand to substitute the ligand which is trans to…

Q: Using the reaction below and using Ligand 6 to determine the HNMR shown below. Ligand 6 is a…

A: The given proton NMR is not the correct NMR for the ligand 6. Two protons at 10.116 ppm may be for…

Q: Rank the following complexes from smallest to largest d-orbital splitting i) [Fe(CN)6]3- ii)…

A: The complexes given are (i) [Fe(CN)6]3−, (ii) [Fe(CN)6]4−, (iii) [Fe(Cl)6]4−, (iv) [Ru(CN)6]3−

Q: What is the LFSE for the [Co(bipy)3]Cl2 complex, knowing that $\Delta$o =  11300 cm-1 and P= 22500…

A: LFSE is the ligand field stabilization energy. For the given complex, Co is in +2 state. A strong…

Q: Which of the following complex has the highest effective magnetic moment: K2MnO4 KMnO4 K2MnCl4…

A: The objective of the question is to determine which of the given complexes has the highest effective…

Q: Tetranorbornyl cobalt contains a Co4+ center with four norbornyl groups arranged tetrahedrally…

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Q: A complex only absorbs light with an energy of 4.42x10-19 J. What color do we see for the complex?

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Q: Three absorption bands were observed at 11200, 18350, 29000 cm-1 in the electronic spectrum of the…

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Q: 7. The following questions pertain to the octahedral spin crossover complex [Co(OH- terpy)2]2+…

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Q: Which atom is a common linkage site in polydentate ligands?

A: Polydendate ligands are those ligands which have more than 2 donar atoms .

Q: Discuss the binding mode and geometry of the imido and cyclopentadienyl ligands in the tungsten…

A: Imido Ligands:Binding Mode: Imido ligands typically bind to metal centers through a double bond…

Q: Which of the following ligands will bind to a transition metal center most strongly? Group of answer…

A: Transition metal : are generally electron deficient (Example : Ti3+ ).  Therefore that ligand which…