Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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make a table for each of the spectra, please include:
- the experimental wavelength, literature wavelength, peaks characteristics, assignment)
- PLEASE INCLUDE LITERATURE WAVELENGTH
Transcribed Image Text:### Infrared Spectrum Analysis of p-Bromoaniline
**Header Information:**
- **HIT-NO:** 1388
- **SCORE:** ( )
- **SDBS-NO:** 1272
- **IR-NIDA:** 02110
- **Method:** KBR DISC
**Compound Name:** p-Bromoaniline
**Molecular Formula:** C₆H₆BrN
**Spectrum Analysis:**
- The graph presents the infrared (IR) spectrum of p-bromoaniline. The y-axis represents transmittance (%) and the x-axis signifies wavenumbers (cm⁻¹), ranging from 4000 to 400 cm⁻¹.
**Key Peaks:**
The spectrum shows several distinct peaks, indicating various functional group vibrations:
- Strong peak at 3476 cm⁻¹
- Noticeable peak at 3384 cm⁻¹
- Peaks between 3000 cm⁻¹ to 1500 cm⁻¹ indicating the presence of different C-H and N-H stretches.
- A significant pattern of peaks between 1500 cm⁻¹ and 500 cm⁻¹, identifying distinct bending vibrations including those of the aromatic ring.
**Data Table:**
| Wavenumber (cm⁻¹) | Intensity (%) |
|-------------------|---------------|
| 3476 | 36 |
| 3384 | 19 |
| 3191 | 70 |
| 3087 | 74 |
| 2570 | 77 |
| 1630 | 77 |
| 1614 | 9 |
| 1593 | 39 |
| 1537 | 81 |
| 1489 | 4 |
| 1436 | 72 |
| 1314 | 84 |
| 1287 | 15 |
| 1183 | 38 |
| 1124 | 72 |
| 1112 | 81 |
| 1070 | 38 |
| 1065 | 64 |
| 1051 | 84 |
| 1007 | 74 |
| 926 | 06 |
| 820 | 16 |
| 818
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