Luminol dianion is treated with hydrogen peroxide and potassium ferricyanide which results in formation of triplet excited state dianion and liberation of nitrogen gas. Once formed, the triplet dianion undergoes intersystem crossing to form a singlet excited state. As the molecule returns to the ground state, it emits bluish-green light. 9. (1) Draw the curved arrow mechanism showing conversion of B to C. (Hint: Think of Diels- Alder reaction mechanism) :0

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question

Please explain diels alder mechanism

Luminol dianion is treated with hydrogen peroxide and potassium ferricyanide which results in formation
of triplet excited state dianion and liberation of nitrogen gas. Once formed, the triplet dianion undergoes
intersystem crossing to form a singlet excited state. As the molecule returms to the ground state, it emits
bluish-green light.
9. (1) Draw the curved arrow mechanism showing conversion of B to C. (Hint: Think of Diels-
Alder reaction mechanism)
Transcribed Image Text:Luminol dianion is treated with hydrogen peroxide and potassium ferricyanide which results in formation of triplet excited state dianion and liberation of nitrogen gas. Once formed, the triplet dianion undergoes intersystem crossing to form a singlet excited state. As the molecule returms to the ground state, it emits bluish-green light. 9. (1) Draw the curved arrow mechanism showing conversion of B to C. (Hint: Think of Diels- Alder reaction mechanism)
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 2 steps with 2 images

Blurred answer
Knowledge Booster
UV and Visible Spectroscopy
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY