Liquid ammonia autoionizes like water:2NH₃(l) →NH₄⁺(am)+NH₂⁻(am) where (am) represents solvation by NH₃.(a) Write the ion-product constant expression, Kₐₘ.(b) What are the strongest acid and base that can exist in NH₃(l)?(c) HNO₃ and HCOOH are leveled in NH₃(l). Explain with equations.(d) At the boiling point (-33°C), Kₐₘ=5.1X10⁻²⁷. Calculate[NH₄⁺ ] at this temperature.(e) Pure sulfuric acid also autoionizes. Write the ion-product constant expression, K(sulf), and find the concentration of the con-jugate base at 20°C (K(sulf) =2.7X10⁻⁴ at 20°C).

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
icon
Concept explainers
Question

Liquid ammonia autoionizes like water:2NH₃(l) →NH₄⁺(am)+NH₂⁻(am) where (am) represents solvation by NH₃.(a) Write the ion-product constant expression, Kₐₘ.(b) What are the strongest acid and base that can exist in NH₃(l)?(c) HNO₃ and HCOOH are leveled in NH₃(l). Explain with equations.(d) At the boiling point (-33°C), Kₐₘ=5.1X10⁻²⁷. Calculate[NH₄⁺ ] at this temperature.(e) Pure sulfuric acid also autoionizes. Write the ion-product constant expression, K(sulf), and find the concentration of the con-jugate base at 20°C (K(sulf) =2.7X10⁻⁴ at 20°C).

Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 3 steps with 5 images

Blurred answer
Knowledge Booster
Ionic Equilibrium
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY