Answered: Lindlar Pd (a) CH3(CH,),C=C(CH,),COOH +…

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Each of the following reactions has been reported in the chemical literature and proceeds in good yield. What are the principal organic products of each reaction? In some of the exercises more than one diastereomer may be possible, but one of them is either the major product or the only product. For those reactions in which one diastereomer is formed preferentially, indicate its expected stereochemistry.

Lindlar Pd
(a) CH3(CH,),C=C(CH,),COOH + H,
1. Li, NH3 .
(b) CH;(CH,),C=C(CH,),COOH
2. H+
Pt
(c) (Z)-CH;(CH,),CH=CH(CH,),COCH,CH; + H2
1. LIAIH4
(d) (Z)-CH3(CH2);CHCH¿CH=CH(CH2),COCH3
2. H20
ÓH
(e) (Z)-CH3(CH2),CH=CH(CH2);COOH + C,H¿COOH
(f) Product of part (e) + H3O*→
1. OsO4, (CH3);COOH, HO-
2. H*
(g) (Z)-CH3(CH2),CH=CH(CH2),COOH
1. B2H6, diglyme
(h)
2. Н-О, НО
1. B2H6, diglyme
2. H-Ог, НО
-OH
HCI
H20
C2H3402
(j)
CH;O-
CH30

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