Learning Objectives: 1. Present and discuss Charles' Law 2. Show mathematically the relationship between volume (V) and temperature (T) at constant pressure of a gas. 3. Apply Charles' Law in solving real ife problems related to the V-T relationship in gases.

Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Learning Objectives:
1. Present and discuss Charles' Law
2. Show mathematically the relationship between volume (V) and temperature (T)
at constant pressure of a gas.
3. Apply Charles' Law in solving real life problems related to the V-T relationship in
gases.
Let Us Discover
In this Learning Activity Sheet (LAS), you will learn about how gases behave in different
conditions using the assumptions in Kinetic Molecular Theory. You will leam the relationships
between volume, temperature, and pressure using Charles' Law.
CHARLES' LAW
Have you tried releasing a sky lantern on occasion? How does it work? Sky lanterns are
small hot air balloons used on special celebrations. It works on the concept of volume-
temperature relationship. The flame below the sky lantern, warms up and expands the air
inside it, causing it to become less dense, float up and stay airborne until the flame is
extinguished.
The volume-temperature relationship in gases such as air, was studied by Jacques
Charles through a series of experiments in 1787. In his experiments, he found out that volume
of trapped gases varies directly with temperature. In generalization, Charles' Law states that at
constant pressure, the volume (V) of gas is directiy proportional to the Kelvin of temperature (T).
Mathematically, the law is expressed as Va T. Removing the proportionality symbol (a)
and replace with equality sign (=) with a constant (k), the equation will be:
V- KT or
where: V is the volume, Tis the temperature in Kelvin
GSC-CID-LRMS-ESSLM, v.r. 02.00, Effective April 21, 2021
If the volume- temperature ratios are the same in the initial and final condition,
Vr.
then you will arrive at k (initial) = k (final), where: k (initial), T and k (final), V,and the
V V.
final equation is = V, or (Vi)+ (T;) – (V;)+ (T:) or V, x Tr-V: x T.
Let Us Try
Let us explore Charles' Law through this simple experiment. In this experiment, you will be able
to determine how volume and temperature at constant pressure are related.
Activity 1: Oh! It's MAGICI
Procedure:
1. Prepare these materials: 1 pc ice wrapper, rubbing
alcohol, 2 paper cups and some hot and iced water.
2. Get the ice wrapper, spray a little amount of alcohol
inside, inflate and tie its opening to trap the air in it. Set
aside.
3. Next, fill the first cup with hot water and the second cup
with iced water. Place the two cups on a plane
surface/table.
4. Observe what will happen to the inflated ice wrapper as
you place it over the cup of iced water for a minute.
Record your observation in the table below.
5. Then observe what will happen to the inflated ice wrapper
as you remove it over the cup of iced water and then
place it over the cup of hot water for a minute. Record
your observation in the table below.
Condition
Temperature of Water
Volume of the Wrapper
(High or Low)
(Increase/decrease)
Cold Water
Hot Water
Guide Questions:
1. Based on your observation, how is the volume of the trapped air inside the ice wrapper
affected by the change in temperature of the water (Generalization)?
2. Recall your previous lesson. How would you describe the kinetic energy of the air
molecules when it is subjected to high temperature? to low temperature (Elaboration)?
GSC-CID-LRMS-ESSLM, v.r. O2.00, Effective April 21, 2021
Transcribed Image Text:Learning Objectives: 1. Present and discuss Charles' Law 2. Show mathematically the relationship between volume (V) and temperature (T) at constant pressure of a gas. 3. Apply Charles' Law in solving real life problems related to the V-T relationship in gases. Let Us Discover In this Learning Activity Sheet (LAS), you will learn about how gases behave in different conditions using the assumptions in Kinetic Molecular Theory. You will leam the relationships between volume, temperature, and pressure using Charles' Law. CHARLES' LAW Have you tried releasing a sky lantern on occasion? How does it work? Sky lanterns are small hot air balloons used on special celebrations. It works on the concept of volume- temperature relationship. The flame below the sky lantern, warms up and expands the air inside it, causing it to become less dense, float up and stay airborne until the flame is extinguished. The volume-temperature relationship in gases such as air, was studied by Jacques Charles through a series of experiments in 1787. In his experiments, he found out that volume of trapped gases varies directly with temperature. In generalization, Charles' Law states that at constant pressure, the volume (V) of gas is directiy proportional to the Kelvin of temperature (T). Mathematically, the law is expressed as Va T. Removing the proportionality symbol (a) and replace with equality sign (=) with a constant (k), the equation will be: V- KT or where: V is the volume, Tis the temperature in Kelvin GSC-CID-LRMS-ESSLM, v.r. 02.00, Effective April 21, 2021 If the volume- temperature ratios are the same in the initial and final condition, Vr. then you will arrive at k (initial) = k (final), where: k (initial), T and k (final), V,and the V V. final equation is = V, or (Vi)+ (T;) – (V;)+ (T:) or V, x Tr-V: x T. Let Us Try Let us explore Charles' Law through this simple experiment. In this experiment, you will be able to determine how volume and temperature at constant pressure are related. Activity 1: Oh! It's MAGICI Procedure: 1. Prepare these materials: 1 pc ice wrapper, rubbing alcohol, 2 paper cups and some hot and iced water. 2. Get the ice wrapper, spray a little amount of alcohol inside, inflate and tie its opening to trap the air in it. Set aside. 3. Next, fill the first cup with hot water and the second cup with iced water. Place the two cups on a plane surface/table. 4. Observe what will happen to the inflated ice wrapper as you place it over the cup of iced water for a minute. Record your observation in the table below. 5. Then observe what will happen to the inflated ice wrapper as you remove it over the cup of iced water and then place it over the cup of hot water for a minute. Record your observation in the table below. Condition Temperature of Water Volume of the Wrapper (High or Low) (Increase/decrease) Cold Water Hot Water Guide Questions: 1. Based on your observation, how is the volume of the trapped air inside the ice wrapper affected by the change in temperature of the water (Generalization)? 2. Recall your previous lesson. How would you describe the kinetic energy of the air molecules when it is subjected to high temperature? to low temperature (Elaboration)? GSC-CID-LRMS-ESSLM, v.r. O2.00, Effective April 21, 2021
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