Label a curve of potential energy vs. dihedral angle for the Newman conformations of 2,3-dimethylbutane. In each case, the C-2 to C-3 bond rotates in the clockwise direction. Step 1: Translate line-bond notation to the Newman projection. Step 2: Identify Newman projections for each rotation. "|H Step 3: Identify the relative stability of each Newman projection. Step 4: Construct the energy diagram. Step 3: Identify the relative stability of each Newman projection (continued) Compare the eclipsed Newman projections and determine the relative stability. 0° 120° 240° CH3 CH3 CH3 H3C H H3C D -CH3 D H CH3 H H H3C H3C Select the true statement. 0° is the most stable conformation. 120° and 240° are less stable and have equivalent stability. 0° is the most stable, followed by 120°, then 240° 240° is the most stable, followed by 120°, then 0° 120° and 240° are the most stable and have equivalent stability. 0° is the least stable, H -CH3 CH3 -H CH3
Reactive Intermediates
In chemistry, reactive intermediates are termed as short-lived, highly reactive atoms with high energy. They rapidly transform into stable particles during a chemical reaction. In specific cases, by means of matrix isolation and at low-temperature reactive intermediates can be isolated.
Hydride Shift
A hydride shift is a rearrangement of a hydrogen atom in a carbocation that occurs to make the molecule more stable. In organic chemistry, rearrangement of the carbocation is very easily seen. This rearrangement can be because of the movement of a carbocation to attain stability in the compound. Such structural reorganization movement is called a shift within molecules. After the shifting of carbocation over the different carbon then they form structural isomers of the previous existing molecule.
Vinylic Carbocation
A carbocation where the positive charge is on the alkene carbon is known as the vinyl carbocation or vinyl cation. The empirical formula for vinyl cation is C2H3+. In the vinyl carbocation, the positive charge is on the carbon atom with the double bond therefore it is sp hybridized. It is known to be a part of various reactions, for example, electrophilic addition of alkynes and solvolysis as well. It plays the role of a reactive intermediate in these reactions.
Cycloheptatrienyl Cation
It is an aromatic carbocation having a general formula, [C7 H7]+. It is also known as the aromatic tropylium ion. Its name is derived from the molecule tropine, which is a seven membered carbon atom ring. Cycloheptatriene or tropylidene was first synthesized from tropine.
Stability of Vinyl Carbocation
Carbocations are positively charged carbon atoms. It is also known as a carbonium ion.
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