k2 2. CA+B k3 3. C P (a) Using the steady-state approximation - proposed mechanism to form product, . steady-state concentration of the intermediate: rate of formation of P: differential rate law from the
k2 2. CA+B k3 3. C P (a) Using the steady-state approximation - proposed mechanism to form product, . steady-state concentration of the intermediate: rate of formation of P: differential rate law from the
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:The following reaction is provided to form the product, P:
kl
1. A+B C
k2
2. CA+B
k3
3. CP
(a) Using the steady-state approximation -
proposed mechanism to form product, .
steady-state concentration of the intermediate:
rate of formation of P:
differential rate law from the
![The following reaction is provided to form the product, P:
kl
1. A+B C
k2
2. C A+ B
k3
3. CP
(b) Using the accuracy of steady-state approximation for the intermediate, find the
rate of change of A and show that it is first order with respect to both A and B also
second-order overall.
rate of change of A: [A]_](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fb4299bab-cfe6-4df1-82fa-bdefd18a2ba9%2F644b4b72-9bc9-428a-ae22-d2d5cee2c596%2F747kqyt_processed.jpeg&w=3840&q=75)
Transcribed Image Text:The following reaction is provided to form the product, P:
kl
1. A+B C
k2
2. C A+ B
k3
3. CP
(b) Using the accuracy of steady-state approximation for the intermediate, find the
rate of change of A and show that it is first order with respect to both A and B also
second-order overall.
rate of change of A: [A]_
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