Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Draw the product of the reactions

Transcribed Image Text:Certainly! Below is a transcription and explanation of the chemical reactions depicted in the image:
---
### Reaction k:
**Reactant:**
- Methyl acetate (CH₃COOCH₃)
**Reagent:**
- Water (H₂O)
**Product:**
- This is a hydrolysis reaction, which typically produces acetic acid (CH₃COOH) and methanol, with Hydrochloric acid (HCl) as a byproduct.
### Reaction l:
**Reactant:**
- Cyclohexyl acetate (cyclohexyl ethanoate)
**Reagent:**
- Thionyl chloride (SOCl₂)
**Product:**
- This reaction typically converts the ester into an acyl chloride, resulting in cyclohexanoyl chloride.
### Reaction m:
**Reactant:**
- Glutaric acid (HOOC-(CH₂)₃-COOH)
**Condition:**
- Heat
**Product:**
- The reaction under heat might result in the formation of an anhydride or breakdown into cyclic compounds depending on the reaction conditions.
### Reaction n:
**Reactant:**
- Acetic acid (CH₃COOH)
**Reagent:**
- Methylamine (CH₃NH₂)
**Product:**
- This is a typical amidation reaction leading to the formation of an amide such as acetamide.
### Reaction o:
**Reactant:**
- Cyclohexyl acetate (Cyclohexyl methanoate, CH₃COOC₆H₁₁)
**Reagent:**
- Water (H₂O) with Sodium hydroxide (NaOH)
**Product:**
- This represents a saponification reaction, which yields cyclohexanol and sodium acetate.
---
These reactions are representative of various organic chemistry processes such as hydrolysis, chlorination, heat-induced transformations, amidation, and saponification, each used extensively in both educational and industrial settings for synthesizing different chemical compounds.

Transcribed Image Text:### Transcription and Explanation of Organic Chemistry Reactions
**Reaction p:**
- **Reactants:**
- Molecule containing an amide group (`NH`) attached to a carbonyl group (structure includes a methyl group adjacent to the carbonyl).
- Reactants include water (`H2O`), hydrochloric acid (`HCl`), and heat.
- **Reaction Description:**
The reaction involves the hydrolysis of an amide under acidic conditions. The amide bond is cleaved by heat and presence of hydrochloric acid, transforming the amide into a carboxylic acid.
**Reaction q:**
- **Reactants:**
- Cyclohexylamino ketone structure (`NH2` group attached to a carbonyl-carbon adjacent to a cyclohexyl ring).
- Reactant is thionyl chloride (`SOCl2`).
- **Reaction Description:**
This reaction describes the transformation of an amine to a corresponding acyl chloride using thionyl chloride. The `NH2` group is replaced by a chlorine atom, forming an acyl chloride derivative.
**Reaction r:**
- **Reactants:**
- Molecule with an amine group (`NH2`) attached to a carbonyl group.
- Reactants are water (`H2O`) and sodium hydroxide (`NaOH`).
- **Reaction Description:**
This depicts the basic hydrolysis (saponification) of an amide. The amide reacts with base to form a carboxylate salt and release ammonia or amine.
**Reaction s:**
- **Reactants:**
- Molecule with a nitrile group (`C≡N`) attached to an alkyl group.
- Reactants include water (`H2O`) and hydrochloric acid (`HCl`).
- **Reaction Description:**
This reaction demonstrates the acidic hydrolysis of a nitrile. Under these conditions, the nitrile is converted to a carboxylic acid.
These reactions illustrate common transformations in organic chemistry used to convert amides and nitriles to carboxylic acids and their derivatives, employing both acidic and basic conditions.
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