k. .ا m. OCH3 ملی H2O HCI SOCI2 مليلة heat

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Draw the product of the reactions 

Certainly! Below is a transcription and explanation of the chemical reactions depicted in the image:

---

### Reaction k:

**Reactant:**  
- Methyl acetate (CH₃COOCH₃)

**Reagent:**  
- Water (H₂O)

**Product:**  
- This is a hydrolysis reaction, which typically produces acetic acid (CH₃COOH) and methanol, with Hydrochloric acid (HCl) as a byproduct.

### Reaction l:

**Reactant:**  
- Cyclohexyl acetate (cyclohexyl ethanoate)

**Reagent:**  
- Thionyl chloride (SOCl₂)

**Product:**  
- This reaction typically converts the ester into an acyl chloride, resulting in cyclohexanoyl chloride.

### Reaction m:

**Reactant:**  
- Glutaric acid (HOOC-(CH₂)₃-COOH)

**Condition:**  
- Heat

**Product:**  
- The reaction under heat might result in the formation of an anhydride or breakdown into cyclic compounds depending on the reaction conditions.

### Reaction n:

**Reactant:**  
- Acetic acid (CH₃COOH)

**Reagent:**  
- Methylamine (CH₃NH₂)

**Product:**  
- This is a typical amidation reaction leading to the formation of an amide such as acetamide.

### Reaction o:

**Reactant:**  
- Cyclohexyl acetate (Cyclohexyl methanoate, CH₃COOC₆H₁₁)

**Reagent:**  
- Water (H₂O) with Sodium hydroxide (NaOH)

**Product:**  
- This represents a saponification reaction, which yields cyclohexanol and sodium acetate.

---

These reactions are representative of various organic chemistry processes such as hydrolysis, chlorination, heat-induced transformations, amidation, and saponification, each used extensively in both educational and industrial settings for synthesizing different chemical compounds.
Transcribed Image Text:Certainly! Below is a transcription and explanation of the chemical reactions depicted in the image: --- ### Reaction k: **Reactant:** - Methyl acetate (CH₃COOCH₃) **Reagent:** - Water (H₂O) **Product:** - This is a hydrolysis reaction, which typically produces acetic acid (CH₃COOH) and methanol, with Hydrochloric acid (HCl) as a byproduct. ### Reaction l: **Reactant:** - Cyclohexyl acetate (cyclohexyl ethanoate) **Reagent:** - Thionyl chloride (SOCl₂) **Product:** - This reaction typically converts the ester into an acyl chloride, resulting in cyclohexanoyl chloride. ### Reaction m: **Reactant:** - Glutaric acid (HOOC-(CH₂)₃-COOH) **Condition:** - Heat **Product:** - The reaction under heat might result in the formation of an anhydride or breakdown into cyclic compounds depending on the reaction conditions. ### Reaction n: **Reactant:** - Acetic acid (CH₃COOH) **Reagent:** - Methylamine (CH₃NH₂) **Product:** - This is a typical amidation reaction leading to the formation of an amide such as acetamide. ### Reaction o: **Reactant:** - Cyclohexyl acetate (Cyclohexyl methanoate, CH₃COOC₆H₁₁) **Reagent:** - Water (H₂O) with Sodium hydroxide (NaOH) **Product:** - This represents a saponification reaction, which yields cyclohexanol and sodium acetate. --- These reactions are representative of various organic chemistry processes such as hydrolysis, chlorination, heat-induced transformations, amidation, and saponification, each used extensively in both educational and industrial settings for synthesizing different chemical compounds.
### Transcription and Explanation of Organic Chemistry Reactions

**Reaction p:**
- **Reactants:** 
  - Molecule containing an amide group (`NH`) attached to a carbonyl group (structure includes a methyl group adjacent to the carbonyl).
  - Reactants include water (`H2O`), hydrochloric acid (`HCl`), and heat.
  
- **Reaction Description:**
  The reaction involves the hydrolysis of an amide under acidic conditions. The amide bond is cleaved by heat and presence of hydrochloric acid, transforming the amide into a carboxylic acid.

**Reaction q:**
- **Reactants:** 
  - Cyclohexylamino ketone structure (`NH2` group attached to a carbonyl-carbon adjacent to a cyclohexyl ring).
  - Reactant is thionyl chloride (`SOCl2`).
  
- **Reaction Description:**
  This reaction describes the transformation of an amine to a corresponding acyl chloride using thionyl chloride. The `NH2` group is replaced by a chlorine atom, forming an acyl chloride derivative.

**Reaction r:**
- **Reactants:** 
  - Molecule with an amine group (`NH2`) attached to a carbonyl group.
  - Reactants are water (`H2O`) and sodium hydroxide (`NaOH`).

- **Reaction Description:**
  This depicts the basic hydrolysis (saponification) of an amide. The amide reacts with base to form a carboxylate salt and release ammonia or amine.

**Reaction s:**
- **Reactants:**
  - Molecule with a nitrile group (`C≡N`) attached to an alkyl group.
  - Reactants include water (`H2O`) and hydrochloric acid (`HCl`).

- **Reaction Description:**
  This reaction demonstrates the acidic hydrolysis of a nitrile. Under these conditions, the nitrile is converted to a carboxylic acid.

These reactions illustrate common transformations in organic chemistry used to convert amides and nitriles to carboxylic acids and their derivatives, employing both acidic and basic conditions.
Transcribed Image Text:### Transcription and Explanation of Organic Chemistry Reactions **Reaction p:** - **Reactants:** - Molecule containing an amide group (`NH`) attached to a carbonyl group (structure includes a methyl group adjacent to the carbonyl). - Reactants include water (`H2O`), hydrochloric acid (`HCl`), and heat. - **Reaction Description:** The reaction involves the hydrolysis of an amide under acidic conditions. The amide bond is cleaved by heat and presence of hydrochloric acid, transforming the amide into a carboxylic acid. **Reaction q:** - **Reactants:** - Cyclohexylamino ketone structure (`NH2` group attached to a carbonyl-carbon adjacent to a cyclohexyl ring). - Reactant is thionyl chloride (`SOCl2`). - **Reaction Description:** This reaction describes the transformation of an amine to a corresponding acyl chloride using thionyl chloride. The `NH2` group is replaced by a chlorine atom, forming an acyl chloride derivative. **Reaction r:** - **Reactants:** - Molecule with an amine group (`NH2`) attached to a carbonyl group. - Reactants are water (`H2O`) and sodium hydroxide (`NaOH`). - **Reaction Description:** This depicts the basic hydrolysis (saponification) of an amide. The amide reacts with base to form a carboxylate salt and release ammonia or amine. **Reaction s:** - **Reactants:** - Molecule with a nitrile group (`C≡N`) attached to an alkyl group. - Reactants include water (`H2O`) and hydrochloric acid (`HCl`). - **Reaction Description:** This reaction demonstrates the acidic hydrolysis of a nitrile. Under these conditions, the nitrile is converted to a carboxylic acid. These reactions illustrate common transformations in organic chemistry used to convert amides and nitriles to carboxylic acids and their derivatives, employing both acidic and basic conditions.
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