Just as pH is the negative logarithm of [H3O+]. PK is the negative logarithm of Ka. pKa log Ka The Henderson-Hasselbalch equation is used. buffer solutions: pH=pK₂ + log calculate the pH of base (acid Notice that the pH of a buffer has a value close to the PKa of the acid. differing only by the logarithm of the concentration ratio [base]/[acid]. The Henderson-Hasselbalch equation in terms of pOH and PK is similar. (base) pOH =pK+log acid Part A Acetic acid has a K₁ of 1.8 x 105. Three acetic acid/acetate buffer solutions, A, B. and C, were made using varying concentrations: A. [acetic acid] ten times greater than [acetate]. B. [acetate] ten times greater than [acetic acid], and c. [acetate] [acetic acid]. Match each buffer to the expected pH Drag the appropriate items to their respective bins. ▸ View Available Hint(s) [acetic acid] ten times greater than [acetate] pH = 3.74 [acetate] ten times greater than [acetic acid] pH = 4.74 Reset Help [acetate] [acetic acid] pH = 5.74
Just as pH is the negative logarithm of [H3O+]. PK is the negative logarithm of Ka. pKa log Ka The Henderson-Hasselbalch equation is used. buffer solutions: pH=pK₂ + log calculate the pH of base (acid Notice that the pH of a buffer has a value close to the PKa of the acid. differing only by the logarithm of the concentration ratio [base]/[acid]. The Henderson-Hasselbalch equation in terms of pOH and PK is similar. (base) pOH =pK+log acid Part A Acetic acid has a K₁ of 1.8 x 105. Three acetic acid/acetate buffer solutions, A, B. and C, were made using varying concentrations: A. [acetic acid] ten times greater than [acetate]. B. [acetate] ten times greater than [acetic acid], and c. [acetate] [acetic acid]. Match each buffer to the expected pH Drag the appropriate items to their respective bins. ▸ View Available Hint(s) [acetic acid] ten times greater than [acetate] pH = 3.74 [acetate] ten times greater than [acetic acid] pH = 4.74 Reset Help [acetate] [acetic acid] pH = 5.74
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question
![**Base/Acid Ratios in Buffers**
In buffer chemistry, understanding the relationship between base and acid concentrations is crucial. Here's an overview of the key concepts and an interactive exercise to reinforce them.
**Henderson-Hasselbalch Equation**
- **pH Calculation:**
Just as pH is the negative logarithm of [H₃O⁺], pKₐ is the negative logarithm of Kₐ.
\[
pK_a = -\log K_a
\]
The Henderson-Hasselbalch equation is used to calculate the pH of buffer solutions:
\[
\text{pH} = pK_a + \log \left(\frac{\text{[base]}}{\text{[acid]}}\right)
\]
Notice that the pH of a buffer is close to the pKₐ of the acid, differing only by the logarithm of the concentration ratio [base]/[acid].
- **pOH Calculation:**
The Henderson-Hasselbalch equation in terms of pOH and pK_b is similar:
\[
\text{pOH} = pK_b + \log \left(\frac{\text{[acid]}}{\text{[base]}}\right)
\]
**Interactive Exercise: Part A**
Given:
- Acetic acid with a \(K_a\) of \(1.8 \times 10^{-5}\).
- Three buffer solutions (A, B, C) with varying concentrations:
A. [acetic acid] ten times greater than [acetate].
B. [acetate] ten times greater than [acetic acid].
C. [acetate] = [acetic acid].
**Task:**
Match each buffer to the expected pH. Drag the appropriate items to their respective bins.
- **Bins:**
- pH = 3.74
- pH = 4.74
- pH = 5.74
Use this interactive module to solidify your understanding of buffer solutions and pH calculations.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fa68ce928-ba22-44f3-b7e8-79ff119a3cf3%2Fca9ff896-3588-4795-a2a9-a21233372e42%2F38py1pq_processed.jpeg&w=3840&q=75)
Transcribed Image Text:**Base/Acid Ratios in Buffers**
In buffer chemistry, understanding the relationship between base and acid concentrations is crucial. Here's an overview of the key concepts and an interactive exercise to reinforce them.
**Henderson-Hasselbalch Equation**
- **pH Calculation:**
Just as pH is the negative logarithm of [H₃O⁺], pKₐ is the negative logarithm of Kₐ.
\[
pK_a = -\log K_a
\]
The Henderson-Hasselbalch equation is used to calculate the pH of buffer solutions:
\[
\text{pH} = pK_a + \log \left(\frac{\text{[base]}}{\text{[acid]}}\right)
\]
Notice that the pH of a buffer is close to the pKₐ of the acid, differing only by the logarithm of the concentration ratio [base]/[acid].
- **pOH Calculation:**
The Henderson-Hasselbalch equation in terms of pOH and pK_b is similar:
\[
\text{pOH} = pK_b + \log \left(\frac{\text{[acid]}}{\text{[base]}}\right)
\]
**Interactive Exercise: Part A**
Given:
- Acetic acid with a \(K_a\) of \(1.8 \times 10^{-5}\).
- Three buffer solutions (A, B, C) with varying concentrations:
A. [acetic acid] ten times greater than [acetate].
B. [acetate] ten times greater than [acetic acid].
C. [acetate] = [acetic acid].
**Task:**
Match each buffer to the expected pH. Drag the appropriate items to their respective bins.
- **Bins:**
- pH = 3.74
- pH = 4.74
- pH = 5.74
Use this interactive module to solidify your understanding of buffer solutions and pH calculations.
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