Jerry carried out a vapor liquid equilibrium experiment for tert-butyl ether (1)/dichloromethane (2) system at 308.15 K. Data in table below were obtained. (Refer attachment) Please calculate the fugacity from the experimental data. Analyze the ideality of the system. Show the result in a graph and give reason to your answer.

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
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Jerry carried out a vapor liquid equilibrium experiment for tert-butyl ether (1)/dichloromethane (2) system at 308.15 K. Data in table below were obtained. (Refer attachment)

Please calculate the fugacity from the experimental data. Analyze the ideality of the system. Show the result in a graph and give reason to your answer.

 

P (kPa)
X1
y1
85.265
82.202
0.0579
0.0253
76.719
0.1665
0.0804
72.422
0.2482
0.1314
68.005
0.3322
0.1975
65.096
0.388
0.2457
59.651
0.5036
0.3686
56.833
0.5749
0.4564
53.689
0.6736
0.5882
51.620
0.7676
0.7176
50.455
0.8476
0.8238
49.926
0.9093
0.9002
49.720
0.9529
0.9502
49.624
1
1
Transcribed Image Text:P (kPa) X1 y1 85.265 82.202 0.0579 0.0253 76.719 0.1665 0.0804 72.422 0.2482 0.1314 68.005 0.3322 0.1975 65.096 0.388 0.2457 59.651 0.5036 0.3686 56.833 0.5749 0.4564 53.689 0.6736 0.5882 51.620 0.7676 0.7176 50.455 0.8476 0.8238 49.926 0.9093 0.9002 49.720 0.9529 0.9502 49.624 1 1
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