iv. Assign formal charges to the atoms in the following structures and decide which the more important contributor to the resonance hybrid is. (a) (b) H H C=N=N c-N=N H H

Introduction to General, Organic and Biochemistry
11th Edition
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Chapter3: Chemical Bonds
Section: Chapter Questions
Problem 3.87P: 3-87 Consider the molecule boron trffluoride, BF3. (a) Write a Lewis structure for BF3. (b) Predict...
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iv. Assign formal charges to the atoms in the following structures
and decide which the more important contributor to the
resonance hybrid is.
(a)
(b)
H
H
c=N=N
c-N=N
H.
H
v. What factor accounts for each of the following differences in
bond length?
(a) I, has a longer bond than Br,.
(b) C-N bonds are shorter than C-C bonds.
(c) H C bonds are shorter than the C-O bond.
(d) The C-O bond in formaldehyde, H,C=0, is longer than the bond in carbon monoxide,
C=O.
Transcribed Image Text:iv. Assign formal charges to the atoms in the following structures and decide which the more important contributor to the resonance hybrid is. (a) (b) H H c=N=N c-N=N H. H v. What factor accounts for each of the following differences in bond length? (a) I, has a longer bond than Br,. (b) C-N bonds are shorter than C-C bonds. (c) H C bonds are shorter than the C-O bond. (d) The C-O bond in formaldehyde, H,C=0, is longer than the bond in carbon monoxide, C=O.
Exercise 7
i. Draw Lewis structures for (a) ; (b) HNO,.
ii. Draw Lewis structures for (a) ASH3; (b) HCIO,; and (c)
H,AsO4.
iii. Assign formal charges to each atom in the following structures:
:ö:
ö=s-ö:
(b)
(e) ö=s-0:
Transcribed Image Text:Exercise 7 i. Draw Lewis structures for (a) ; (b) HNO,. ii. Draw Lewis structures for (a) ASH3; (b) HCIO,; and (c) H,AsO4. iii. Assign formal charges to each atom in the following structures: :ö: ö=s-ö: (b) (e) ö=s-0:
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