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iv) Determine the volume change ΔV for the transformation from rhombic to monoclinic sulphur.

iv) Determine the volume change ΔV for the transformation from rhombic to monoclinic sulphur.

Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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iv) Determine the volume change ΔV for the transformation from rhombic to
monoclinic sulphur.
v) Estimate the pressure at wh
ich rhombic and monoclinic sulphur coexist in equilibrium at a temperature of 373 K.
2. Below is the phase diagram of sulphur. At 95.4°C, the densities of rhombic and monoclinic sulphur are 2.07 g cm³ and 1.96 g cm³, whilst the enthalpy change for phase transition from rhombic to monoclinic sulphur is 0.3 kJ mol1. Sulfur 153°C, Liquid 1420 atm 95.4°C 115.21°C 1 atm P Monoclinic 444.6°C 115.2°C, 3.2 x 10-5 atm Rhombic 95.3°C, 5.1 x 10-6 atm Gas T
Transcribed Image Text:2. Below is the phase diagram of sulphur. At 95.4°C, the densities of rhombic and monoclinic sulphur are 2.07 g cm³ and 1.96 g cm³, whilst the enthalpy change for phase transition from rhombic to monoclinic sulphur is 0.3 kJ mol1. Sulfur 153°C, Liquid 1420 atm 95.4°C 115.21°C 1 atm P Monoclinic 444.6°C 115.2°C, 3.2 x 10-5 atm Rhombic 95.3°C, 5.1 x 10-6 atm Gas T
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