It should be true that the way a reaction is written shouldn't affect the outcome of a thermochemical analysis. For example, But what if we wrote it this way (2× larger)? H₂O(g) → H2(g) + 1/2O2(g) Amount at equilibrium Mole fractions we analyzed: 2H₂O(g) → 2H2(g) + O2(g) Would the extent of the reaction (a) change? a. To answer this question, first re-derive the mole fraction table using the 2x equation: H₂O 0₂ H₂ 2na 2(1-α) (2 + a) b. Now rederive Kx in terms of a and set it equal to 8.581 × 10-4¹ to solve for a. 4.q³ (2+a)²-(2-2a) c. Your a is much larger than before! However, if you used Kx = 7.36 x 10-81, you would have found the same a=2.451×10-27 as before. Why is it that the value of the equilibrium constant appears to have changed from 8.581 x 10-4¹ to 7.36 × 10-81? . Hint: A.G° = RT · In(K), which means that the answer isn't so much something is wrong with K, rather its A,Gº.
It should be true that the way a reaction is written shouldn't affect the outcome of a thermochemical analysis. For example, But what if we wrote it this way (2× larger)? H₂O(g) → H2(g) + 1/2O2(g) Amount at equilibrium Mole fractions we analyzed: 2H₂O(g) → 2H2(g) + O2(g) Would the extent of the reaction (a) change? a. To answer this question, first re-derive the mole fraction table using the 2x equation: H₂O 0₂ H₂ 2na 2(1-α) (2 + a) b. Now rederive Kx in terms of a and set it equal to 8.581 × 10-4¹ to solve for a. 4.q³ (2+a)²-(2-2a) c. Your a is much larger than before! However, if you used Kx = 7.36 x 10-81, you would have found the same a=2.451×10-27 as before. Why is it that the value of the equilibrium constant appears to have changed from 8.581 x 10-4¹ to 7.36 × 10-81? . Hint: A.G° = RT · In(K), which means that the answer isn't so much something is wrong with K, rather its A,Gº.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
Related questions
Question
![It should be true that the way a reaction is written shouldn't affect the outcome of a
thermochemical analysis. For example,
But what if we wrote it this way (2× larger)?
H₂O(g) → H2(g) + 1/2O2(g)
Amount at equilibrium
Mole fractions
we analyzed:
2H₂O(g) → 2H2(g) + O2(g)
Would the extent of the reaction (a) change?
a. To answer this question, first re-derive the mole fraction table using the 2× equation:
H₂O
0₂
H₂
2na
2(1-x)
(2 + a)
b. Now rederive Kỵ in terms of a and set it equal to 8.581 x 10-41 to solve for a.
4-α³
(2+a)²-(2-2a)
c. Your a is much larger than before! However, if you used Kx
= 7.36 x 10-81,
you would have found the same a=2.451×10-27 as before. Why is it that the value of the
equilibrium constant appears to have changed from 8.581 x 10-41 to 7.36 x 10-81?
Hint: A.Gº = -RT · In(K), which means that the answer isn't so much something is wrong with
K, rather its A.Gº.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Ff5a7063b-ad95-49d7-8786-36f721649130%2F9fcc0d6c-f268-4745-8085-de5ad2f944fd%2Fuqzxkjq_processed.png&w=3840&q=75)
Transcribed Image Text:It should be true that the way a reaction is written shouldn't affect the outcome of a
thermochemical analysis. For example,
But what if we wrote it this way (2× larger)?
H₂O(g) → H2(g) + 1/2O2(g)
Amount at equilibrium
Mole fractions
we analyzed:
2H₂O(g) → 2H2(g) + O2(g)
Would the extent of the reaction (a) change?
a. To answer this question, first re-derive the mole fraction table using the 2× equation:
H₂O
0₂
H₂
2na
2(1-x)
(2 + a)
b. Now rederive Kỵ in terms of a and set it equal to 8.581 x 10-41 to solve for a.
4-α³
(2+a)²-(2-2a)
c. Your a is much larger than before! However, if you used Kx
= 7.36 x 10-81,
you would have found the same a=2.451×10-27 as before. Why is it that the value of the
equilibrium constant appears to have changed from 8.581 x 10-41 to 7.36 x 10-81?
Hint: A.Gº = -RT · In(K), which means that the answer isn't so much something is wrong with
K, rather its A.Gº.
Expert Solution
![](/static/compass_v2/shared-icons/check-mark.png)
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
This is a popular solution!
Trending now
This is a popular solution!
Step by step
Solved in 5 steps
![Blurred answer](/static/compass_v2/solution-images/blurred-answer.jpg)
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Recommended textbooks for you
![Chemistry](https://www.bartleby.com/isbn_cover_images/9781305957404/9781305957404_smallCoverImage.gif)
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
![Chemistry](https://www.bartleby.com/isbn_cover_images/9781259911156/9781259911156_smallCoverImage.gif)
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
![Principles of Instrumental Analysis](https://www.bartleby.com/isbn_cover_images/9781305577213/9781305577213_smallCoverImage.gif)
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
![Chemistry](https://www.bartleby.com/isbn_cover_images/9781305957404/9781305957404_smallCoverImage.gif)
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
![Chemistry](https://www.bartleby.com/isbn_cover_images/9781259911156/9781259911156_smallCoverImage.gif)
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
![Principles of Instrumental Analysis](https://www.bartleby.com/isbn_cover_images/9781305577213/9781305577213_smallCoverImage.gif)
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
![Organic Chemistry](https://www.bartleby.com/isbn_cover_images/9780078021558/9780078021558_smallCoverImage.gif)
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
![Chemistry: Principles and Reactions](https://www.bartleby.com/isbn_cover_images/9781305079373/9781305079373_smallCoverImage.gif)
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
![Elementary Principles of Chemical Processes, Bind…](https://www.bartleby.com/isbn_cover_images/9781118431221/9781118431221_smallCoverImage.gif)
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY