It is possible to generate sulfur ylides in a manner similar to that used to produce phosphonium ylides. For example, treating a sulfonium salt with a strong base gives the sulfur ylide. CH3 strong Ph. base CH3 Ph Br Ph CH3 `CH3 Ph A sulfonium bromide salt A sulfur ylide Sulfur ylides react with ketones to give epoxides. Suggest a mechanism for this reaction. Ph. CH3 CH `st=c CH3 CH, + Ph,S Ph

It is possible to generate sulfur ylides in a manner similar to that used to produce phosphonium ylides. For example, treating a sulfonium salt with a strong base gives the sulfur ylide. CH3 strong Ph. base CH3 Ph Br Ph CH3 `CH3 Ph A sulfonium bromide salt A sulfur ylide Sulfur ylides react with ketones to give epoxides. Suggest a mechanism for this reaction. Ph. CH3 CH `st=c CH3 CH, + Ph,S Ph

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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