It is of interest to decide if an analytical separation of the metal ions can be effected by selective precipitation of carbonates from a solution that is 0.110 M in Fe2+ and 0.105 M in Ba2+, FeCO3 Ksp = 3.50x10-11 BaCO3 Ksp = 8.10x109 To analyze this problem, answer the following questions. (1) What carbonate concentration is needed to precipitate 99.9% of the metal that forms the least soluble carbonate? (2) When 99.9% of the least soluble carbonate has precipitated, will all of the metal that forms the more soluble carbonate still remain in solution? O (3) What is the upper limit on the carbonate ion concentration if the more soluble compound is not to precipitate? M M

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It is of interest to decide if an analytical separation of the metal ions can be effected by selective precipitation of carbonates from
a solution that is 0.110 M in Fe2+ and 0.105 M in Ba²+,
FeCO3
Ksp 3.50x10-11
BaCO3
Ksp = 8.10x109
To analyze this problem, answer the following questions.
(1) What carbonate concentration is needed to precipitate 99.9% of the metal that forms the least soluble carbonate?
(2) When 99.9% of the least soluble carbonate has precipitated, will all of the metal that forms the more soluble carbonate still
remain in solution?
O
(3) What is the upper limit on the carbonate ion concentration if the more soluble compound is not to precipitate?
M
%
M
(4) If the [CO32] is at this upper limit, what percentage of the metal that form the least soluble carbonate remains in solution?
Transcribed Image Text:It is of interest to decide if an analytical separation of the metal ions can be effected by selective precipitation of carbonates from a solution that is 0.110 M in Fe2+ and 0.105 M in Ba²+, FeCO3 Ksp 3.50x10-11 BaCO3 Ksp = 8.10x109 To analyze this problem, answer the following questions. (1) What carbonate concentration is needed to precipitate 99.9% of the metal that forms the least soluble carbonate? (2) When 99.9% of the least soluble carbonate has precipitated, will all of the metal that forms the more soluble carbonate still remain in solution? O (3) What is the upper limit on the carbonate ion concentration if the more soluble compound is not to precipitate? M % M (4) If the [CO32] is at this upper limit, what percentage of the metal that form the least soluble carbonate remains in solution?
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