Isotopic substitution changes the rotational energy levels of a molecule. This phenomenon can be used for precise evaluation of the atomic weight of isotopes. The first line (J = 0) in the pure rotational spectrum of 12C160 and 13C160 are found to be 3.84235 and 3.67337 cm-1, respectively. Calculate the precise atomic weight of 13C given that the precise atomic weight of 160 is 15.9994 and that of 12C is 12.011. (Consider the molecules as rigid rotor and isotopic substitution does not affect the bond length).

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question

Please don't provide handwritten solution

.Isotopic substitution changes the rotational energy levels of a molecule. This phenomenon
can be used for precise evaluation of the atomic weight of isotopes. The first line (J = 0) in the
pure rotational spectrum of 12C160 and 13C160 are found to be 3.84235 and 3.67337 cm-1,
respectively. Calculate the precise atomic weight of 13C given that the precise atomic weight
of 160 is 15.9994 and that of 12C is 12.011. (Consider the molecules as rigid rotor and isotopic
substitution does not affect the bond length).
Transcribed Image Text:.Isotopic substitution changes the rotational energy levels of a molecule. This phenomenon can be used for precise evaluation of the atomic weight of isotopes. The first line (J = 0) in the pure rotational spectrum of 12C160 and 13C160 are found to be 3.84235 and 3.67337 cm-1, respectively. Calculate the precise atomic weight of 13C given that the precise atomic weight of 160 is 15.9994 and that of 12C is 12.011. (Consider the molecules as rigid rotor and isotopic substitution does not affect the bond length).
Expert Solution
steps

Step by step

Solved in 3 steps with 11 images

Blurred answer
Knowledge Booster
Atomic Structure and Spectra
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY