Isotopic substitution changes the rotational energy levels of a molecule. This phenomenon can be used for precise evaluation of the atomic weight of isotopes. The first line (J = 0) in the pure rotational spectrum of 12C160 and 13C160 are found to be 3.84235 and 3.67337 cm-1, respectively. Calculate the precise atomic weight of 13C given that the precise atomic weight of 160 is 15.9994 and that of 12C is 12.011. (Consider the molecules as rigid rotor and isotopic substitution does not affect the bond length).

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.Isotopic substitution changes the rotational energy levels of a molecule. This phenomenon
can be used for precise evaluation of the atomic weight of isotopes. The first line (J = 0) in the
pure rotational spectrum of 12C160 and 13C160 are found to be 3.84235 and 3.67337 cm-1,
respectively. Calculate the precise atomic weight of 13C given that the precise atomic weight
of 160 is 15.9994 and that of 12C is 12.011. (Consider the molecules as rigid rotor and isotopic
substitution does not affect the bond length).
Transcribed Image Text:.Isotopic substitution changes the rotational energy levels of a molecule. This phenomenon can be used for precise evaluation of the atomic weight of isotopes. The first line (J = 0) in the pure rotational spectrum of 12C160 and 13C160 are found to be 3.84235 and 3.67337 cm-1, respectively. Calculate the precise atomic weight of 13C given that the precise atomic weight of 160 is 15.9994 and that of 12C is 12.011. (Consider the molecules as rigid rotor and isotopic substitution does not affect the bond length).
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