Intermolecular forces of interaction influence the algebraic signs (“+” or “-“) and the magnitude of DHsoln. Consider a solution composed of liquid-A and liquid-B, such that the intermolecular force between molecules A and B is stronger than either between A and A or B and B.   (a) Does the formation of an A-B solution result in a positive DHsoln (implying an endothermic process) or a negative DHsoln (implying an exothermic process)? Explain your reasoning.   (b) If you have a solution that contains 50% of each by mole quantity, would the boiling point of the solution be higher or lower than the average boiling points of the individual liquids? Explain.

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1-Intermolecular forces of interaction influence the algebraic signs (“+” or “-“) and the magnitude of DHsoln. Consider a solution composed of liquid-A and liquid-B, such that the intermolecular force between molecules A and B is stronger than either between A and A or B and B.

  (a) Does the formation of an A-B solution result in a positive DHsoln (implying an endothermic process) or a negative DHsoln (implying an exothermic process)? Explain your reasoning.

  (b) If you have a solution that contains 50% of each by mole quantity, would the boiling point of the solution be higher or lower than the average boiling points of the individual liquids? Explain.

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