In UV/Vis spectrometry calculating the iron in an iron tablet, when preparing the sample, an iron tablet is added to HCl and heated. Next, it is filtered and diluted. Ammonia solution is added t set the pH to 3.5, then hydroquinone and o- phenanthroline are added. After waiting 10 minutes the a bsorba nce is measured

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In UV/Vis spectrometry calculating the iron in an
iron tablet, when preparing the sample, an iron
tablet is added to HCl and heated. Next, it is
filtered and diluted. Ammonia solution is added to
set the pH to 3.5, then hydroquinone and o-
phenanthroline are added. After waiting 10
minutes, the absorbance is measured.
(1) Why is the sample heated after HCI is added?
What would happen if it is not heated?
(2) What sort of side products are produced that
filtration is necessary?
(3) Why is the pH set at 3.5? Why is such a pH
necessary for the iron to react with hydroquinone
and o-phenanthroline? (please be specific)
(4) Why do we have to wait 10 minutes before
measuring the absorbance?
Thank you!
Transcribed Image Text:In UV/Vis spectrometry calculating the iron in an iron tablet, when preparing the sample, an iron tablet is added to HCl and heated. Next, it is filtered and diluted. Ammonia solution is added to set the pH to 3.5, then hydroquinone and o- phenanthroline are added. After waiting 10 minutes, the absorbance is measured. (1) Why is the sample heated after HCI is added? What would happen if it is not heated? (2) What sort of side products are produced that filtration is necessary? (3) Why is the pH set at 3.5? Why is such a pH necessary for the iron to react with hydroquinone and o-phenanthroline? (please be specific) (4) Why do we have to wait 10 minutes before measuring the absorbance? Thank you!
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