In the lower troposphere, ozone is one of the components of photochemical smog. It is generated in air when nitrogen dioxide, formed by the oxidation of nitrogen monoxide from car exhaust, reacts by the following mechanism: (1) NO2(g) NO(g) + 0(g) (2) O(g) + O2(g) O3(g) where k = 6.0 x 103s; kz = 1.0 x 10° L/mol's; [NO2] = 4.0 x 10 M; and [O2] = 3.0 x 10 2 M. %3D Assuming the rate of formation of atomic oxygen in step 1 equals the rate of its consumption in step 2, calculate the concentration of atomic oxygen [O]. Enter your answer in scientific notation. x 10 (select) M

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**Photochemical Smog and Ozone Formation in the Troposphere**

**Mechanism of Ozone Formation:**

Photochemical smog is a complex mixture of pollutants, with ozone (O₃) being a significant component. In the lower troposphere, ozone is generated through the following mechanism involving nitrogen dioxide (NO₂), which originates from the oxidation of nitrogen monoxide in car exhaust:

1. **Reaction 1:**
   \[
   \text{NO}_2(\text{g}) \xrightarrow{k_1} \text{NO}(\text{g}) + \text{O}(\text{g})
   \]

2. **Reaction 2:**
   \[
   \text{O}(\text{g}) + \text{O}_2(\text{g}) \xrightarrow{k_2} \text{O}_3(\text{g})
   \]

**Rate Constants and Concentrations:**

- Rate constant for Reaction 1 (\(k_1\)) = \(6.0 \times 10^{-3} \, \text{s}^{-1}\)
- Rate constant for Reaction 2 (\(k_2\)) = \(1.0 \times 10^{6} \, \text{L/mol} \cdot \text{s}\)
- Concentration of NO₂ = \(4.0 \times 10^{-9} \, \text{M}\)
- Concentration of O₂ = \(3.0 \times 10^{-2} \, \text{M}\)

**Task:**

Assume the rate of formation of atomic oxygen (\(O\)) in step 1 equals the rate of its consumption in step 2. Calculate the concentration of atomic oxygen \([O]\). Enter your answer in scientific notation.

\[ \_\_\_\_ \times 10^{( \_\_\_\_ )} \, \text{M} \]
Transcribed Image Text:**Photochemical Smog and Ozone Formation in the Troposphere** **Mechanism of Ozone Formation:** Photochemical smog is a complex mixture of pollutants, with ozone (O₃) being a significant component. In the lower troposphere, ozone is generated through the following mechanism involving nitrogen dioxide (NO₂), which originates from the oxidation of nitrogen monoxide in car exhaust: 1. **Reaction 1:** \[ \text{NO}_2(\text{g}) \xrightarrow{k_1} \text{NO}(\text{g}) + \text{O}(\text{g}) \] 2. **Reaction 2:** \[ \text{O}(\text{g}) + \text{O}_2(\text{g}) \xrightarrow{k_2} \text{O}_3(\text{g}) \] **Rate Constants and Concentrations:** - Rate constant for Reaction 1 (\(k_1\)) = \(6.0 \times 10^{-3} \, \text{s}^{-1}\) - Rate constant for Reaction 2 (\(k_2\)) = \(1.0 \times 10^{6} \, \text{L/mol} \cdot \text{s}\) - Concentration of NO₂ = \(4.0 \times 10^{-9} \, \text{M}\) - Concentration of O₂ = \(3.0 \times 10^{-2} \, \text{M}\) **Task:** Assume the rate of formation of atomic oxygen (\(O\)) in step 1 equals the rate of its consumption in step 2. Calculate the concentration of atomic oxygen \([O]\). Enter your answer in scientific notation. \[ \_\_\_\_ \times 10^{( \_\_\_\_ )} \, \text{M} \]
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