in the following four reactions (I-IV), two are invalid. (a) In the space below, identify the two invalid reactions by the corresponding numeral, and (b) explain why each is invalid or a synthetic trap. (Feel free to use a drawing to illustrate your point.) I. I. OH CuLi NaOH Br H20 I. ОН IV. 1. LAH 2. H20 HO
in the following four reactions (I-IV), two are invalid. (a) In the space below, identify the two invalid reactions by the corresponding numeral, and (b) explain why each is invalid or a synthetic trap. (Feel free to use a drawing to illustrate your point.) I. I. OH CuLi NaOH Br H20 I. ОН IV. 1. LAH 2. H20 HO
Chemistry
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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![In the following four reactions (I-IV), two are invalid.
(a) Identify the two invalid reactions by the corresponding numeral, and (b) explain why each is invalid or a synthetic trap. (Feel free to use a drawing to illustrate your point.)
### Reaction I:
A starting compound with two ketone groups undergoes a reaction in the presence of NaOH and H₂O, resulting in a cyclic compound with an alcohol and a ketone group.
### Reaction II:
A compound with a bromine atom undergoes a reaction with a dialkylcuprate (R₂CuLi), resulting in an alkene.
### Reaction III:
A benzaldehyde derivative is reduced using 1. LAH (lithium aluminum hydride) and 2. H₂O, resulting in a primary alcohol.
### Reaction IV:
An amide group reacts with a combination of an amine (NH) and another base, yielding an imine.
**Notes on Diagrams:**
- **Reaction I Diagram:** Features a linear diketone transforming into a cyclized compound with hydroxyl and ketone groups.
- **Reaction III Diagram:** Shows a benzaldehyde derivative being reduced to form a benzyl alcohol using LAH as the reducing agent.
Analyze the mechanisms and identify errors or invalid expectations in the specified reactions.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fa1308c18-827c-41a1-b2ec-8a88ef0ba574%2F5f070b9c-12b5-413f-a495-91dfb02bddd1%2Fqbpadro_processed.jpeg&w=3840&q=75)
Transcribed Image Text:In the following four reactions (I-IV), two are invalid.
(a) Identify the two invalid reactions by the corresponding numeral, and (b) explain why each is invalid or a synthetic trap. (Feel free to use a drawing to illustrate your point.)
### Reaction I:
A starting compound with two ketone groups undergoes a reaction in the presence of NaOH and H₂O, resulting in a cyclic compound with an alcohol and a ketone group.
### Reaction II:
A compound with a bromine atom undergoes a reaction with a dialkylcuprate (R₂CuLi), resulting in an alkene.
### Reaction III:
A benzaldehyde derivative is reduced using 1. LAH (lithium aluminum hydride) and 2. H₂O, resulting in a primary alcohol.
### Reaction IV:
An amide group reacts with a combination of an amine (NH) and another base, yielding an imine.
**Notes on Diagrams:**
- **Reaction I Diagram:** Features a linear diketone transforming into a cyclized compound with hydroxyl and ketone groups.
- **Reaction III Diagram:** Shows a benzaldehyde derivative being reduced to form a benzyl alcohol using LAH as the reducing agent.
Analyze the mechanisms and identify errors or invalid expectations in the specified reactions.
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