In the Dumas method for determining the molar mass of an unknown volatile liquid, a sample of a volatile liquid that boils below 100 oC is vaporized in a boiling water bath and the mass of the vapor required to fill the flask is determined. The following data was collected:  Flask Volume 100.0 +100.0 + 79.6 mL = 279.6 mL Mass of Flask + Cap 143.85 g Mass of Flask + Condensed Liquid 144.95 g Mass of Condensed Liquid 1.10 g Temperature of Water Bath

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1.) In the Dumas method for determining the molar mass of an unknown volatile liquid, a sample of a volatile liquid that boils below 100 oC is vaporized in a boiling water bath and the mass of the vapor required to fill the flask is determined. The following data was collected: 

Flask Volume

100.0 +100.0 + 79.6 mL = 279.6 mL

Mass of Flask + Cap

143.85 g

Mass of Flask + Condensed Liquid

144.95 g

Mass of Condensed Liquid

1.10 g

Temperature of Water Bath (oC) 

84.1 oC

Barometric Pressure (atm)

0.985 atm

 

a.) What is the molar mass of the unknown? 

b.) What will its temperature be when the pressure is 1.20 atm and the volume is 250.0 mL?

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