In quantum mechanics, there is a method to find approximations to the ground state and some excited states of an atom. The method requires one to use a "trial" function of some parameter and calculate the value of these parame- ters for which the expectation value of the energy is minimum. Let the trial function be: P(a) = Ae-ar To calculate the expectation value, one needs to find the inner product of the trial function with the Hamiltonian (i.e. Total energy) acting on itself, as defined by: | $(a)HÞ(a}r°dr Using gamma function, calculate the potential term of the inner product in terms of A, a, e, and eo: A?e? re-2ar dr 4neo

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In quantum mechanics, there is a method to find approximations to the ground
state and some excited states of an atom. The method requires one to use a
"trial" function of some parameter and calculate the value of these parame-
ters for which the expectation value of the energy is minimum. Let the trial
function be:
P(a) = Ae-ar
To calculate the expectation value, one needs to find the inner product of the
trial function with the Hamiltonian (i.e. Total energy) acting on itself, as
defined by:
Using gamma function, calculate the potential term of the inner product in
terms of A, a, e, and eo:
A?e?
roo
- 2ar
dr
re
0.
Transcribed Image Text:In quantum mechanics, there is a method to find approximations to the ground state and some excited states of an atom. The method requires one to use a "trial" function of some parameter and calculate the value of these parame- ters for which the expectation value of the energy is minimum. Let the trial function be: P(a) = Ae-ar To calculate the expectation value, one needs to find the inner product of the trial function with the Hamiltonian (i.e. Total energy) acting on itself, as defined by: Using gamma function, calculate the potential term of the inner product in terms of A, a, e, and eo: A?e? roo - 2ar dr re 0.
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