Introductory Chemistry: A Foundation
9th Edition
ISBN:9781337399425
Author:Steven S. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Donald J. DeCoste
Chapter20: Organic Chemistry
Section: Chapter Questions
Problem 125AP
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Question
ANSWER BOTH
![In order to form a tertiary alcohol, excess CHsMgBr could react with
which one(s) of these compounds?
CH
B
0-CH
Write "highest" under the compound which would have the highest
boiling point.
Write "lowest" under the compound which would have the lowest boiling point.
1-heptanol
octane
hexanoic acid
Write "most" under the alkene which is most stable and "least" under the alkene
which is least stable.
CH3
CH3
HC
CH2
CH3
Write "most" under the one which would be most reactive toward
hydrolysis.
Write "least" under the one which would be least reactive toward hydrolysis.
H3C
H;C
0-CH3
H;C.
NH2
Write "least" under the one which would be least soluble in water.
1-pentanol
Write "most" under the one which would be most soluble in water.
pentane
1-propanol
Write "most" under the one which is most acidic.
Write "least" under the one which is least acidic.
cyclohexanol
phenol
Cyclohexane](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fdbf2dd13-9bb3-486d-9c8e-94d97f70c6a8%2F5b50fac0-93e2-434d-adb1-717b39425180%2F1t1opng_processed.jpeg&w=3840&q=75)
Transcribed Image Text:In order to form a tertiary alcohol, excess CHsMgBr could react with
which one(s) of these compounds?
CH
B
0-CH
Write "highest" under the compound which would have the highest
boiling point.
Write "lowest" under the compound which would have the lowest boiling point.
1-heptanol
octane
hexanoic acid
Write "most" under the alkene which is most stable and "least" under the alkene
which is least stable.
CH3
CH3
HC
CH2
CH3
Write "most" under the one which would be most reactive toward
hydrolysis.
Write "least" under the one which would be least reactive toward hydrolysis.
H3C
H;C
0-CH3
H;C.
NH2
Write "least" under the one which would be least soluble in water.
1-pentanol
Write "most" under the one which would be most soluble in water.
pentane
1-propanol
Write "most" under the one which is most acidic.
Write "least" under the one which is least acidic.
cyclohexanol
phenol
Cyclohexane
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