In ¹H NMR, increased electron density in a C-H sigma bond causes A. Deshielding and an increased precessional frequency. B. Shielding and an increased precessional frequency. C. Deshielding and a decreased precessional frequency. D. Shielding and a decreased precessional frequency. A mass spectrum will show an M+2 peak molecular about 1/3 the intensity of the molecular peak if A. the molecule contains chlorine. B. the molecule contains an odd number of nitrogen atoms. C. the molecular ion is unstable. D. the molecule contains an even number of nitrogen atoms. E. the molecule contains bromine. Which of the following compounds would be expected to show a mass spectrum with a molecular ion having an odd mass-to-charge ratio? I. NH Br CI -Br H₂N NH2 III. IV. II. NH₂ A. I only B. II only C. III only D. IV only E. more than one of the above

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In ¹H NMR, increased electron density in a C-H sigma bond causes
A. Deshielding and an increased precessional frequency.
B. Shielding and an increased precessional frequency.
C. Deshielding and a decreased precessional frequency.
D. Shielding and a decreased precessional frequency.
A mass spectrum will show an M+2 peak molecular about 1/3 the intensity of the molecular
peak if
A. the molecule contains chlorine.
B. the molecule contains an odd number of nitrogen atoms.
C. the molecular ion is unstable.
D. the molecule contains an even number of nitrogen atoms.
E. the molecule contains bromine.
Which of the following compounds would be expected to show a mass spectrum with a
molecular ion having an odd mass-to-charge ratio?
I.
NH
Br
CI
-Br
H₂N
NH2
III.
IV.
II.
NH₂
A. I only
B. II only
C. III only
D. IV only
E. more than one of the above
Transcribed Image Text:In ¹H NMR, increased electron density in a C-H sigma bond causes A. Deshielding and an increased precessional frequency. B. Shielding and an increased precessional frequency. C. Deshielding and a decreased precessional frequency. D. Shielding and a decreased precessional frequency. A mass spectrum will show an M+2 peak molecular about 1/3 the intensity of the molecular peak if A. the molecule contains chlorine. B. the molecule contains an odd number of nitrogen atoms. C. the molecular ion is unstable. D. the molecule contains an even number of nitrogen atoms. E. the molecule contains bromine. Which of the following compounds would be expected to show a mass spectrum with a molecular ion having an odd mass-to-charge ratio? I. NH Br CI -Br H₂N NH2 III. IV. II. NH₂ A. I only B. II only C. III only D. IV only E. more than one of the above
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