In general, real gases behave most ideally at _____(high/low) temperatures and _____(high/low) pressures.The behavior of real gases can be described using the van der Waals equation[P + (n2a/V2)](V-nb) = nRTThe values of a and b are given below for the two real gases nitrogen and carbon dioxide.The gas in which deviations from ideal behavior due to intermolecular forces are expected to be the largest is _________(nitrogen/carbon dioxide).The gas that would be expected to behave least like an ideal gas at high pressures is _________(nitrogen/carbon dioxide). gas a (L2atm/mol2) b (L/mol) N2 1.39 3.91×10-2 CO2 3.59 4.27×10-2

Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter1: Gases And The Zeroth Law Of Thermodynamics
Section: Chapter Questions
Problem 1.21E: Pressures of gases in mixtures are referred to as partial pressures and are additive. 1.00 L of He...
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In general, real gases behave most ideally at _____(high/low) temperatures and _____(high/low) pressures.

The behavior of real gases can be described using the van der Waals equation

[P + (n2a/V2)](V-nb) = nRT

The values of a and b are given below for the two real gases nitrogen and carbon dioxide.

The gas in which deviations from ideal behavior due to intermolecular forces are expected to be the largest is _________(nitrogen/carbon dioxide).

The gas that would be expected to behave least like an ideal gas at high pressures is _________(nitrogen/carbon dioxide).

gas

a (L2atm/mol2)

b (L/mol)

N2

1.39

3.91×10-2

CO2

3.59

4.27×10-2

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