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In Deacon process, gas phase reaction was carried out in isothermal batch reactor to form chlorine (Cl2) and water (H2O) according to the reaction equation below. 4HC1 + 0, → 2Cl, + 2H20 An equal molar of HCI and O2 are fed to the reactor with total pressure of 4.7 atm and 300 °C as reaction temperature. By taking HCl as limiting reactant, the following experimental data were recorded from constant batch reactor volume: Table 1 Experimental data in an isothermal batch reactor 100 200 300 t (min) P (atm) 50 150 250 2.35 1.78 1.44 1.20 1.04 0.916 0.817 Rate law of the above reaction respond to -Ta=KCA°CB®, in which B is zero order with respect to oxygen. Given R as 0.082 atm. dm/mol. K. Construct a stoichiometric table and determine the reaction order and the rate constant using numerical method (differentiation).

In Deacon process, gas phase reaction was carried out in isothermal batch reactor to form chlorine (Cl2) and water (H2O) according to the reaction equation below. 4HC1 + 0, → 2Cl, + 2H20 An equal molar of HCI and O2 are fed to the reactor with total pressure of 4.7 atm and 300 °C as reaction temperature. By taking HCl as limiting reactant, the following experimental data were recorded from constant batch reactor volume: Table 1 Experimental data in an isothermal batch reactor 100 200 300 t (min) P (atm) 50 150 250 2.35 1.78 1.44 1.20 1.04 0.916 0.817 Rate law of the above reaction respond to -Ta=KCA°CB®, in which B is zero order with respect to oxygen. Given R as 0.082 atm. dm/mol. K. Construct a stoichiometric table and determine the reaction order and the rate constant using numerical method (differentiation).

Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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determine the reaction order and the rate constant using numerical method(differentiation)

In Deacon process, gas phase reaction was carried out in isothermal batch reactor to form chlorine (Cl2) and water (H2O) according to the reaction equation below. 4HCI + 02 → 2Cl, + 2H20 An equal molar of HCI and O2 are fed to the reactor with total pressure of 4.7 atm and 300 °C as reaction temperature. By taking HCl as limiting reactant, the following experimental data were recorded from constant batch reactor volume: Table 1 Experimental data in an isothermal batch reactor t (min) 50 100 150 200 250 300 P (atm) 2.35 1.78 1.44 1.20 1.04 0.916 0.817 Rate law of the above reaction respond to -TA=KCA°CBP, in which B is zero order with respect to oxygen. Given R as 0.082 atm. dm/mol. K. Construct a stoichiometric table and determine the reaction order and the rate constant using numerical method (differentiation).
Transcribed Image Text:In Deacon process, gas phase reaction was carried out in isothermal batch reactor to form chlorine (Cl2) and water (H2O) according to the reaction equation below. 4HCI + 02 → 2Cl, + 2H20 An equal molar of HCI and O2 are fed to the reactor with total pressure of 4.7 atm and 300 °C as reaction temperature. By taking HCl as limiting reactant, the following experimental data were recorded from constant batch reactor volume: Table 1 Experimental data in an isothermal batch reactor t (min) 50 100 150 200 250 300 P (atm) 2.35 1.78 1.44 1.20 1.04 0.916 0.817 Rate law of the above reaction respond to -TA=KCA°CBP, in which B is zero order with respect to oxygen. Given R as 0.082 atm. dm/mol. K. Construct a stoichiometric table and determine the reaction order and the rate constant using numerical method (differentiation).
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