In Deacon process, gas phase reaction was carried out in isothermal batch reactor to form chlorine (Cl2) and water (H2O) according to the reaction equation below. 4HC1 + 02 → 2Cl, + 2H,0 An equal molar of HCI and O2 are fed to the reactor with total pressure of 4.7 atm and 300 °C as reaction temperature. By taking HCI as limiting reactant, the following experimental data were recorded from constant batch reactor volume:
In Deacon process, gas phase reaction was carried out in isothermal batch reactor to form chlorine (Cl2) and water (H2O) according to the reaction equation below. 4HC1 + 02 → 2Cl, + 2H,0 An equal molar of HCI and O2 are fed to the reactor with total pressure of 4.7 atm and 300 °C as reaction temperature. By taking HCI as limiting reactant, the following experimental data were recorded from constant batch reactor volume:
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
Related questions
Question
Hello. Please help me with this problem.
Transcribed Image Text:In Deacon process, gas phase reaction was carried out in isothermal batch reactor
to form chlorine (Cl2) and water (H2O) according to the reaction equation below.
4HCI + 02 → 2Cl, + 2H20
An equal molar of HCI and O2 are fed to the reactor with total pressure of 4.7 atm
and 300 °C as reaction temperature. By taking HCI as limiting reactant, the following
experimental data were recorded from constant batch reactor volume:
Table 1 Experimental data in an isothermal batch reactor
t (min)
P (atm)
50
100
150
200
250
300
2.35
1.78
1.44
1.20
1.04
0.916 0.817
Rate law of the above reaction respond to -TA=KCA°CBP, in which B is zero order with
respect to oxygen. Given R as 0.082 atm. dm/mol. K.
Construct a stoichiometric table and determine the reaction order and the rate
constant using numerical method (differentiation).
Expert Solution
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
This is a popular solution!
Trending now
This is a popular solution!
Step by step
Solved in 3 steps with 3 images
Recommended textbooks for you
Introduction to Chemical Engineering Thermodynami…
Chemical Engineering
ISBN:
9781259696527
Author:
J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:
McGraw-Hill Education
Elementary Principles of Chemical Processes, Bind…
Chemical Engineering
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY
Elements of Chemical Reaction Engineering (5th Ed…
Chemical Engineering
ISBN:
9780133887518
Author:
H. Scott Fogler
Publisher:
Prentice Hall
Introduction to Chemical Engineering Thermodynami…
Chemical Engineering
ISBN:
9781259696527
Author:
J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:
McGraw-Hill Education
Elementary Principles of Chemical Processes, Bind…
Chemical Engineering
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY
Elements of Chemical Reaction Engineering (5th Ed…
Chemical Engineering
ISBN:
9780133887518
Author:
H. Scott Fogler
Publisher:
Prentice Hall
Industrial Plastics: Theory and Applications
Chemical Engineering
ISBN:
9781285061238
Author:
Lokensgard, Erik
Publisher:
Delmar Cengage Learning
Unit Operations of Chemical Engineering
Chemical Engineering
ISBN:
9780072848236
Author:
Warren McCabe, Julian C. Smith, Peter Harriott
Publisher:
McGraw-Hill Companies, The