In Deacon process, gas phase reaction was carried out in isothermal batch reactor to form chlorine (Cl2) and water (H2O) according to the reaction equation below. 4HC1 + 02 → 2Cl, + 2H,0 An equal molar of HCI and O2 are fed to the reactor with total pressure of 4.7 atm and 300 °C as reaction temperature. By taking HCI as limiting reactant, the following experimental data were recorded from constant batch reactor volume:

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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In Deacon process, gas phase reaction was carried out in isothermal batch reactor
to form chlorine (Cl2) and water (H2O) according to the reaction equation below.
4HCI + 02 → 2Cl, + 2H20
An equal molar of HCI and O2 are fed to the reactor with total pressure of 4.7 atm
and 300 °C as reaction temperature. By taking HCI as limiting reactant, the following
experimental data were recorded from constant batch reactor volume:
Table 1 Experimental data in an isothermal batch reactor
t (min)
P (atm)
50
100
150
200
250
300
2.35
1.78
1.44
1.20
1.04
0.916 0.817
Rate law of the above reaction respond to -TA=KCA°CBP, in which B is zero order with
respect to oxygen. Given R as 0.082 atm. dm/mol. K.
Construct a stoichiometric table and determine the reaction order and the rate
constant using numerical method (differentiation).
Transcribed Image Text:In Deacon process, gas phase reaction was carried out in isothermal batch reactor to form chlorine (Cl2) and water (H2O) according to the reaction equation below. 4HCI + 02 → 2Cl, + 2H20 An equal molar of HCI and O2 are fed to the reactor with total pressure of 4.7 atm and 300 °C as reaction temperature. By taking HCI as limiting reactant, the following experimental data were recorded from constant batch reactor volume: Table 1 Experimental data in an isothermal batch reactor t (min) P (atm) 50 100 150 200 250 300 2.35 1.78 1.44 1.20 1.04 0.916 0.817 Rate law of the above reaction respond to -TA=KCA°CBP, in which B is zero order with respect to oxygen. Given R as 0.082 atm. dm/mol. K. Construct a stoichiometric table and determine the reaction order and the rate constant using numerical method (differentiation).
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