In basic aqueous solution the reaction I + OCI- → Cl¯ + OI- follows a rate law that is consistent with the following mechanism: OCI (aq) + H2O(€) НОСlag) + ОН (ag) (fast equilibrium) k-1 k2 I (aq) + HOCI(aq) HOI(aq) + CI¯(aq) (slow) ks OH"(aq) + HOI(aq) H¿O(€) + OI¯(aq) (fast) What rate law is predicted by this mechanism?

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In basic aqueous solution the reaction
I + OCI- → Cl¯ + OI-
Transcribed Image Text:In basic aqueous solution the reaction I + OCI- → Cl¯ + OI-
follows a rate law that is consistent with the following mechanism:
OCI (aq) + H2O(€)
НОСlag) + ОН (ag)
(fast equilibrium)
k-1
k2
I (aq) + HOCI(aq)
HOI(aq) + CI¯(aq)
(slow)
ks
OH"(aq) + HOI(aq)
H¿O(€) + OI¯(aq)
(fast)
What rate law is predicted by this mechanism?
Transcribed Image Text:follows a rate law that is consistent with the following mechanism: OCI (aq) + H2O(€) НОСlag) + ОН (ag) (fast equilibrium) k-1 k2 I (aq) + HOCI(aq) HOI(aq) + CI¯(aq) (slow) ks OH"(aq) + HOI(aq) H¿O(€) + OI¯(aq) (fast) What rate law is predicted by this mechanism?
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