In a laboratory experiment, students synthesized a new compound and found that when 10.17 grams of the compound were dissolved in 267.9 grams of benzene, the solution began to freeze at 4.952 °C. The compound was also found to be nonvolatile and a non-electrolyte.
In a laboratory experiment, students synthesized a new compound and found that when 10.17 grams of the compound were dissolved in 267.9 grams of benzene, the solution began to freeze at 4.952 °C. The compound was also found to be nonvolatile and a non-electrolyte.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![**Understanding the Freezing Point Depression Method to Determine Molecular Weight**
The freezing point of benzene, \( \text{C}_6\text{H}_6 \), is \( 5.500 \, ^\circ \text{C} \) at 1 atmosphere. The cryoscopic constant (\(K_f\)) for benzene is \(5.12 \, ^\circ \text{C/m}\).
In a laboratory experiment, students synthesized a new compound and found that when \(10.17\) grams of the compound were dissolved in \(267.9\) grams of benzene, the solution began to freeze at \(4.952 \, ^\circ \text{C}\). The compound was also found to be nonvolatile and a non-electrolyte.
**Question:**
What is the molecular weight determined for this compound?
**Details:**
- Mass of compound: \(10.17 \, \text{g}\)
- Mass of benzene: \(267.9 \, \text{g}\)
- Freezing point of pure benzene: \(5.500 \, ^\circ \text{C}\)
- Freezing point of solution: \(4.952 \, ^\circ \text{C}\)
- Cryoscopic constant (\(K_f\)) of benzene: \(5.12 \, ^\circ \text{C/m}\)
**Steps to Solve the Problem:**
1. Calculate the freezing point depression (ΔTf):
\[ \Delta T_f = T_f^\circ - T_f \]
where:
\[ T_f^\circ \] = freezing point of the pure solvent \[ (5.500\, ^\circ\text{C}) \]
\[ T_f \] = freezing point of the solution \[ (4.952\, ^\circ\text{C}) \]
2. Use the equation for freezing point depression:
\[ \Delta T_f = K_f \cdot m \]
where:
\[ K_f \] = cryoscopic constant \( (5.12\, ^\circ \text{C/m}) \)
\[ m \] = molality of the solution \(\left(\text{moles of solute} / \text{kg of solvent}\right)\)
3. Calculate the molality (m) of the solution:
\[ m = \frac{\Delta T_f}{K_f}](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F60358686-21d1-41ff-a93a-9ba59c7b6516%2Ff3c4ea14-eacd-42ae-9bcd-26de0bbff006%2Fxupch74.jpeg&w=3840&q=75)
Transcribed Image Text:**Understanding the Freezing Point Depression Method to Determine Molecular Weight**
The freezing point of benzene, \( \text{C}_6\text{H}_6 \), is \( 5.500 \, ^\circ \text{C} \) at 1 atmosphere. The cryoscopic constant (\(K_f\)) for benzene is \(5.12 \, ^\circ \text{C/m}\).
In a laboratory experiment, students synthesized a new compound and found that when \(10.17\) grams of the compound were dissolved in \(267.9\) grams of benzene, the solution began to freeze at \(4.952 \, ^\circ \text{C}\). The compound was also found to be nonvolatile and a non-electrolyte.
**Question:**
What is the molecular weight determined for this compound?
**Details:**
- Mass of compound: \(10.17 \, \text{g}\)
- Mass of benzene: \(267.9 \, \text{g}\)
- Freezing point of pure benzene: \(5.500 \, ^\circ \text{C}\)
- Freezing point of solution: \(4.952 \, ^\circ \text{C}\)
- Cryoscopic constant (\(K_f\)) of benzene: \(5.12 \, ^\circ \text{C/m}\)
**Steps to Solve the Problem:**
1. Calculate the freezing point depression (ΔTf):
\[ \Delta T_f = T_f^\circ - T_f \]
where:
\[ T_f^\circ \] = freezing point of the pure solvent \[ (5.500\, ^\circ\text{C}) \]
\[ T_f \] = freezing point of the solution \[ (4.952\, ^\circ\text{C}) \]
2. Use the equation for freezing point depression:
\[ \Delta T_f = K_f \cdot m \]
where:
\[ K_f \] = cryoscopic constant \( (5.12\, ^\circ \text{C/m}) \)
\[ m \] = molality of the solution \(\left(\text{moles of solute} / \text{kg of solvent}\right)\)
3. Calculate the molality (m) of the solution:
\[ m = \frac{\Delta T_f}{K_f}
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