Image belo Culacac)2 Compound. Use It answer the questions. Recall that the spin-orbit coupling (2) value for Cu² is -830 cm d-orbital splitting pattern (square planar) Cú d̟²-y² dzy

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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EPR & Electronic Transitions. The image below is of the Cu(acac)2 compound. Use it to
answer the questions. Recall that the spin-orbit coupling (2) value for Cu²* is -830 cm.
d-orbital splitting pattern
(square planar)
d2-y?
dry
dz
Cú
-dzz, dyz
a. Fill in the d-orbital splitting diagram.
b. Find AE for g, = g = 2.44 for the d,2-y2 to dry transition
c. Find AE for g,xy = 91 = 2.06 for the d,2-y2 to dz transition
d. Sketch the EPR spectrum for Cu(acac)2. Cu (I = 3/2)
Transcribed Image Text:EPR & Electronic Transitions. The image below is of the Cu(acac)2 compound. Use it to answer the questions. Recall that the spin-orbit coupling (2) value for Cu²* is -830 cm. d-orbital splitting pattern (square planar) d2-y? dry dz Cú -dzz, dyz a. Fill in the d-orbital splitting diagram. b. Find AE for g, = g = 2.44 for the d,2-y2 to dry transition c. Find AE for g,xy = 91 = 2.06 for the d,2-y2 to dz transition d. Sketch the EPR spectrum for Cu(acac)2. Cu (I = 3/2)
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