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- Be *(1) the position operator for a particle subjected to a potential of a one-dimensional harmonic oscillator P mox (Ĥ =+ 2m 2 Evaluate [î(t),î(0)] Heisenberg's chart in2) ( Consider an electron trapped in a one-dimensional anharmonic potential. The Hamiltonian for this system is given as: H mw?£? + 2m + B&3 . Regarding the cubic term as being small, apply non- degenerate perturbation theory by letting the perturbation be: A, = ß2³. а) Calculate to first order the ground state energy of this anharmonic oscillator. b) ( | Calculate to second order the ground state energy of this anharmonic oscillator. c) ( Find the lowest order correction to the ground state wave function.. (1) Find the kinetic, potential and total energies of the hydrogen atorn in the 2nd excited level.
- 2. Consider a particle of mass m in an infinite square well, 0(≤ x ≤a). At the time t = 0 the particle is in the ground (n = 1). Then at t> 0 a weak time-dependent external potential is turned on: H' = Axe T(d) Prove that for a classical particle moving from left to right in a box with constant speed v, the average position = (1/T) ff x(t) dt = L/2, where T L/v is the time taken to move from left to right. And = : (1/T) S²x² (t) dt L²/3. Hint: Only consider a particle moving from left x = 0 to right x = L = and do not include the bouncing motion from right to left. The results for left to right are independent of the sense of motion and therefore the same results apply to all the bounces, so that we can prove it for just one sense of motion. Thus, the classical result is obtained from the Quantum solution when n >> 1. That is, for large energies compared to the minimum energy of the wave-particle system. This is usually referred to as the Classical Limit for Large Quantum Numbers.