(iii) State how the use of ¹¹B and ³¹P NMR spectroscopy can be used to confirm the formation of F3B-PD3. This answer requires that you construct labelled line diagrams to predict the NMR spectra in BF3, PD3 and F3B-PD3. (You may assume that the ¹¹B nucleus is 100% abundant as a first approximation). (iv) The molecule PD3 was substituted with one hydrogen to produce PD₂H. State how ¹H NMR spectroscopy can be used to confirm the formation of F3B PD₂H. This answer requires that you construct labelled line diagrams to predict the 'H NMR spectra in the PD₂H and F3B-PD₂H. (You may assume that the ¹¹B nucleus is 100% abundant as a first approximation).
(iii) State how the use of ¹¹B and ³¹P NMR spectroscopy can be used to confirm the formation of F3B-PD3. This answer requires that you construct labelled line diagrams to predict the NMR spectra in BF3, PD3 and F3B-PD3. (You may assume that the ¹¹B nucleus is 100% abundant as a first approximation). (iv) The molecule PD3 was substituted with one hydrogen to produce PD₂H. State how ¹H NMR spectroscopy can be used to confirm the formation of F3B PD₂H. This answer requires that you construct labelled line diagrams to predict the 'H NMR spectra in the PD₂H and F3B-PD₂H. (You may assume that the ¹¹B nucleus is 100% abundant as a first approximation).
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:(iii) State how the use of ¹¹B and ³¹P NMR spectroscopy can be used to confirm the
formation of F3B-PD3. This answer requires that you construct labelled line diagrams
to predict the NMR spectra in BF3, PD3 and F3B-PD3. (You may assume that the ¹¹B
nucleus is 100% abundant as a first approximation).
(iv) The molecule PD3 was substituted with one hydrogen to produce PD₂H. State how ¹H
NMR spectroscopy can be used to confirm the formation of F3B PD₂H. This answer
requires that you construct labelled line diagrams to predict the ¹H NMR spectra in the
PD₂H and F3B-PD₂H. (You may assume that the 11B nucleus is 100% abundant as a
first approximation).
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