If the pH of a 2.54-cm rainfall over 4600 km is 3.50, how many kilograms of sulfuric acid, HSO4, are present, assuming that it is the only acid contributing to the pH? For sulfuric acid, K, is very large and K, is 0.012.
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![Part A
The presence of SO, in the atmosphere and the
sulfuric acid that it produces result in the phenomenon
of acid rain. Uncontaminated rainwater is naturally
acidic and generally has a pH value of about 5.6. The
pH of acid rain is about 4. This acidity has affected
many lakes in northern Europe, the northern United
States, and Canada, reducing fish populations and
affecting other parts of the ecological network within the
lakes and surrounding forests.
If the pH of a 2.54-cm rainfall over 4600 km? is 3.50, how many kilograms of sulfuric acid, H2SO4, are present, assuming that it is the only acid contributing to the pH?
For sulfuric acid, K, is very large and K, is 0.012.
Express your answer to two significant figures and include the appropriate units.
• View Available Hint(s)
The pH of most natural waters containing living
organisms is between 6.5 and 8.5, but freshwater pH
values are far below 6.5 in many parts of the
continental United States. At pH levels below 4.0, all
vertebrates, most invertebrates, and many
microorganisms are destroyed. More than 300 lakes in
New York State contain no fish, and 140 lakes in
Ontario, Canada, are devoid of life. The acid rain that
appears to have killed the organisms in these lakes
originates hundreds of kilometres upwind in the Ohio
Valley and Great Lakes regions. Some of these
regions are recovering as sulfur emissions from fossil
fuel combustion decrease, in part because of the U.S.
Clean Air Act of 1990, which required that power plants
reduce their sulfur emissions by 80%.
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