Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![**NMR Spectrum Analysis Example**
**Question:**
If the molecule giving the \( ^1\text{H} \) NMR spectrum shown below has a total of 10 protons, how many protons are represented by peak I?
**NMR Spectrum Details:**
- **Graph Overview:** The spectrum includes chemical shifts along the x-axis (in ppm, parts per million) and intensity along the y-axis, which reflects the abundance of signals.
- **Peak Identification:**
- **Peak I:** Located between 2 and 3 ppm, which is typically indicative of protons next to electronegative atoms or in certain chemical environments.
- **Peak II:** Located slightly above 1 ppm, potentially representing protons in a different chemical environment, such as aliphatic groups.
- **Integration Curves:** The curved lines above each peak are integration lines that provide a proportional representation of the number of protons corresponding to each peak.
In this specific spectrum, observe that the integration line above Peak I indicates a smaller integration compared to Peak II. This suggests that fewer protons are contributing to Peak I compared to Peak II.
**Solution Explanation:**
To solve the problem, analyze the integration ratio represented by the peak areas:
1. **Total Protons in the Molecule:** 10 protons.
2. **Protons Corresponding to Peak I:** Evaluate the integration.
- If Peak I is shown to be approximately half the area or height of Peak II, it may represent fewer protons. Assume a hypothetical ratio such as 3 protons for Peak I and 7 for Peak II based on visual assessment.
Hence, the number of protons represented by Peak I is likely 3. Such analysis requires precise integration values often provided alongside NMR spectra in research but can be estimated using visual inspection in educational contexts.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F2721ccf2-fbe1-4868-87fa-588e33d78a8e%2F68d4eb2c-a756-4898-aead-ef426e480805%2F2kqv0sc_processed.jpeg&w=3840&q=75)
Transcribed Image Text:**NMR Spectrum Analysis Example**
**Question:**
If the molecule giving the \( ^1\text{H} \) NMR spectrum shown below has a total of 10 protons, how many protons are represented by peak I?
**NMR Spectrum Details:**
- **Graph Overview:** The spectrum includes chemical shifts along the x-axis (in ppm, parts per million) and intensity along the y-axis, which reflects the abundance of signals.
- **Peak Identification:**
- **Peak I:** Located between 2 and 3 ppm, which is typically indicative of protons next to electronegative atoms or in certain chemical environments.
- **Peak II:** Located slightly above 1 ppm, potentially representing protons in a different chemical environment, such as aliphatic groups.
- **Integration Curves:** The curved lines above each peak are integration lines that provide a proportional representation of the number of protons corresponding to each peak.
In this specific spectrum, observe that the integration line above Peak I indicates a smaller integration compared to Peak II. This suggests that fewer protons are contributing to Peak I compared to Peak II.
**Solution Explanation:**
To solve the problem, analyze the integration ratio represented by the peak areas:
1. **Total Protons in the Molecule:** 10 protons.
2. **Protons Corresponding to Peak I:** Evaluate the integration.
- If Peak I is shown to be approximately half the area or height of Peak II, it may represent fewer protons. Assume a hypothetical ratio such as 3 protons for Peak I and 7 for Peak II based on visual assessment.
Hence, the number of protons represented by Peak I is likely 3. Such analysis requires precise integration values often provided alongside NMR spectra in research but can be estimated using visual inspection in educational contexts.
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