Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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If a 0.900 m aqueous solution freezes at -2.00 Celsius, what is the van't Hoff factor, i, of the solute?
i=
![**Colligative Properties**
Constants for freezing-point depression and boiling-point elevation calculations at 1 atm:
| Solvent | Formula | \(K_f\) value* (°C/m) | Normal freezing point (°C) | \(K_b\) value (°C/m) | Normal boiling point (°C) |
|----------------------|-----------|-----------------------|----------------------------|----------------------|--------------------------|
| Water | H₂O | 1.86 | 0.00 | 0.512 | 100.00 |
| Benzene | C₆H₆ | 5.12 | 5.49 | 2.53 | 80.1 |
| Cyclohexane | C₆H₁₂ | 20.8 | 6.59 | 2.92 | 80.7 |
| Ethanol | C₂H₆O | 1.99 | -117.3 | 1.22 | 78.4 |
| Carbon tetrachloride | CCl₄ | 29.8 | -22.9 | 5.03 | 76.8 |
| Camphor | C₁₀H₁₆O | 37.8 | 176 | | |
*When using positive \(K_f\) values, assume that \(\Delta T_f\) is the absolute value of the change in temperature. If you would like \(\Delta T_f\) to be negative, you must use negative \(K_f\) values. Either way, the freezing point of the solution should be lower.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Faa38d3af-d2a1-4c36-a58b-a982b5534c39%2F8be2a2ee-848b-4f8d-9b1f-9fa307decc68%2F4o6qic.jpeg&w=3840&q=75)
Transcribed Image Text:**Colligative Properties**
Constants for freezing-point depression and boiling-point elevation calculations at 1 atm:
| Solvent | Formula | \(K_f\) value* (°C/m) | Normal freezing point (°C) | \(K_b\) value (°C/m) | Normal boiling point (°C) |
|----------------------|-----------|-----------------------|----------------------------|----------------------|--------------------------|
| Water | H₂O | 1.86 | 0.00 | 0.512 | 100.00 |
| Benzene | C₆H₆ | 5.12 | 5.49 | 2.53 | 80.1 |
| Cyclohexane | C₆H₁₂ | 20.8 | 6.59 | 2.92 | 80.7 |
| Ethanol | C₂H₆O | 1.99 | -117.3 | 1.22 | 78.4 |
| Carbon tetrachloride | CCl₄ | 29.8 | -22.9 | 5.03 | 76.8 |
| Camphor | C₁₀H₁₆O | 37.8 | 176 | | |
*When using positive \(K_f\) values, assume that \(\Delta T_f\) is the absolute value of the change in temperature. If you would like \(\Delta T_f\) to be negative, you must use negative \(K_f\) values. Either way, the freezing point of the solution should be lower.
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