Identify which indicator will be suitable for the following titrimetric analyses: a. 0.100 M solution of HOAC (Ka b. 0.0527 M solution of NH4CI (K, = 1.80 x 10³) with 0.100 M NaOH. C. 0.0162 M solution of piperidine hydrochloride (Kp 1.60 x 10*) with 0.100 M NaOH. d. 0.350 M solution of NaOẠC (K, = 1.78 x 10°) with 0.200 M HCI. e. 0.0568 M solution of sodium dichloroacetate (Ka = 3.32 x 102) with 0.200 M HCI. = 1.78 x 10) with 0.100 M NaOH. %3D

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Color change table is given.
Table 2. Some common acid-base indicators
Indicator
Color change with increasing pH
pH range
Picric acid
colorless to yellow
red to yellow
colorless to yellow
red to yellow
yellow to blue
red to yellow
yellow to blue
red to yellow
0.1-0.8
1.2-2.8
Thymol blue
2,6-Dinitrophenol
Methyl yellow
Bromphenol blue
Methyl orange
Bromcresol green
Methyl red
Litmus
2.0-4.0
2.9-4.0
3.0-4.6
3.1-4.4
3.8-5.4
4.2-6.2
4.5-8.3
4.8-5.4
red to blue
purple to green
colorless to yellow
yellow to purple
yellow to blue
red to yellow
yellow to red
p-a-Naphtholphthalein yellow to blue
colorless to red
Methyl purple
p-Nitrophenol
Bromcresol purple
Bromthymol blue
Neutral red
Phenol red
5.0-7.0
5.2-6.8
6.0-7.6
6.8-8.4
7.0-9.0
Phenolphthalein
Thymolphthalein
Alizarin yellow R
8.0-9.6
9.3-10.6
10.1-12.0
colorless to blue
yellow to violet
10.1-12.0
Transcribed Image Text:Table 2. Some common acid-base indicators Indicator Color change with increasing pH pH range Picric acid colorless to yellow red to yellow colorless to yellow red to yellow yellow to blue red to yellow yellow to blue red to yellow 0.1-0.8 1.2-2.8 Thymol blue 2,6-Dinitrophenol Methyl yellow Bromphenol blue Methyl orange Bromcresol green Methyl red Litmus 2.0-4.0 2.9-4.0 3.0-4.6 3.1-4.4 3.8-5.4 4.2-6.2 4.5-8.3 4.8-5.4 red to blue purple to green colorless to yellow yellow to purple yellow to blue red to yellow yellow to red p-a-Naphtholphthalein yellow to blue colorless to red Methyl purple p-Nitrophenol Bromcresol purple Bromthymol blue Neutral red Phenol red 5.0-7.0 5.2-6.8 6.0-7.6 6.8-8.4 7.0-9.0 Phenolphthalein Thymolphthalein Alizarin yellow R 8.0-9.6 9.3-10.6 10.1-12.0 colorless to blue yellow to violet 10.1-12.0
Identify which indicator will be suitable for the following titrimetric analyses:
a. 0.100 M solution of HOAC (K, = 1.78 x 10° ) with 0.100 M NaOH.
b. 0.0527 M solution of NH,CI (K, = 1.80 x 10³) with 0.100 M NaOH.
C. 0.0162 M solution of piperidine hydrochloride (Kp 1.60 x 10*) with 0.100 M NaOH,
d. 0.350 M solution of NaOAc (K, = 1.78 x 10³) with 0.200 M HCI.
e. 0.0568 M solution of sodium dichloroacetate (Ka = 3.32 x 102) with 0.200M HCI.
%3D
%3D
Transcribed Image Text:Identify which indicator will be suitable for the following titrimetric analyses: a. 0.100 M solution of HOAC (K, = 1.78 x 10° ) with 0.100 M NaOH. b. 0.0527 M solution of NH,CI (K, = 1.80 x 10³) with 0.100 M NaOH. C. 0.0162 M solution of piperidine hydrochloride (Kp 1.60 x 10*) with 0.100 M NaOH, d. 0.350 M solution of NaOAc (K, = 1.78 x 10³) with 0.200 M HCI. e. 0.0568 M solution of sodium dichloroacetate (Ka = 3.32 x 102) with 0.200M HCI. %3D %3D
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