Identify the major product of the reaction between 1-butanol and Na. Predict the products for each of the following reactions: DP H₂ A Lindlar's catalyst Consider the following sequence of reactions and identify the structures of compounds A, B, and C. Mg Compound A Compound B E. (CH,,Br) 2) H₂O conc. H₂SO Compound C Heat A O Na B. Identify the major product of the reaction between 1-butanol and potassium tert-butoxide. C. Ot-Bu Product A: о о Identify the bases below that can be used to deprotonate a terminal alkyne. Select all that apply. Product B: BuLi NaOCH3 O NaH NaOH NINH, Explain your choices. ✓ The base(s) selected above is/are weaker than the acetylide base, thus favoring the forward reaction. The base(s) selected above is/are stronger than the acetylide base, thus favoring the reverse reaction. The base(s) selected above is/are weaker than the acetylide base, thus favoring the reverse reaction. The base(s) selected above is/are stronger than the acetylide base, thus favoring the forward reaction. о о th₂ B Pt F. 12.42a Draw the structure of compound 'A Draw Your Solution Propose an efficient synthesis for the following transformation: OH The transformation above can be performed with some reagent or combination of the reagents listed below. Give the necessary reagent(s) in the correct order, as a string of letters (without spaces or punctuation, such as "EBF"). If there is more than one correct solution, provide just one answer. A B C NaOEt t-BuOK PCC, CH2Cl2 D E F 1) MeMgBr 2) H3O Na2Cr2O7, H2SO4, H₂O conc. H2SO4, heat H I TsCl, py 1) BH-THF 2) H₂O₂, H₂O G Propose an efficient synthesis for the following transformation: The transformation above can be performed with some reagent or combination of the reagents listed below. Give the necessary reagent(s) in the correct order, as a string of letters (without spaces or punctuation, such as "EBF"). If there is more than one correct solution, provide just one answer. CAF A B C Mel H2, Lindlar's catalyst NaNH, D E F 1) MeMgBr 1)03 1) R₂BH 2) H₂O* 2) H₂O 2) H2O2, NaOH G 1) EtMgBr 2) H₂O* Н H₂O, H₂SO4, HgSO4 Na2Cr2O7, H₂SO4, H₂O

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Chapter1: Chemical Foundations
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Identify the major product of the reaction between 1-butanol and Na.
Predict the products for each of the following reactions:
DP
H₂
A
Lindlar's
catalyst
Consider the following sequence of reactions and identify the structures of compounds A, B, and C.
Mg
Compound A
Compound B
E.
(CH,,Br)
2) H₂O
conc. H₂SO Compound C
Heat
A
O Na
B.
Identify the major product of the reaction between 1-butanol and potassium tert-butoxide.
C.
Ot-Bu
Product A:
о
о
Identify the bases below that can be used to deprotonate a terminal alkyne. Select all that apply.
Product B:
BuLi
NaOCH3
O NaH
NaOH
NINH,
Explain your choices.
✓
The base(s) selected above is/are weaker than the acetylide base, thus favoring the forward reaction.
The base(s) selected above is/are stronger than the acetylide base, thus favoring the reverse reaction.
The base(s) selected above is/are weaker than the acetylide base, thus favoring the reverse reaction.
The base(s) selected above is/are stronger than the acetylide base, thus favoring the forward reaction.
о
о
th₂
B
Pt
F.
12.42a
Draw the structure of compound 'A
Draw Your Solution
Propose an efficient synthesis for the following transformation:
OH
The transformation above can be performed with some reagent or combination of the reagents listed below. Give the necessary
reagent(s) in the correct order, as a string of letters (without spaces or punctuation, such as "EBF"). If there is more than one correct
solution, provide just one answer.
A
B
C
NaOEt
t-BuOK
PCC, CH2Cl2
D
E
F
1) MeMgBr
2) H3O
Na2Cr2O7,
H2SO4, H₂O
conc. H2SO4, heat
H
I
TsCl, py
1) BH-THF
2) H₂O₂, H₂O
G
Propose an efficient synthesis for the following transformation:
The transformation above can be performed with some reagent or combination of the reagents listed below. Give the necessary
reagent(s) in the correct order, as a string of letters (without spaces or punctuation, such as "EBF"). If there is more than one correct
solution, provide just one answer.
CAF
A
B
C
Mel
H2, Lindlar's catalyst
NaNH,
D
E
F
1) MeMgBr
1)03
1) R₂BH
2) H₂O*
2) H₂O
2) H2O2, NaOH
G
1) EtMgBr
2) H₂O*
Н
H₂O, H₂SO4, HgSO4
Na2Cr2O7,
H₂SO4, H₂O
Transcribed Image Text:Identify the major product of the reaction between 1-butanol and Na. Predict the products for each of the following reactions: DP H₂ A Lindlar's catalyst Consider the following sequence of reactions and identify the structures of compounds A, B, and C. Mg Compound A Compound B E. (CH,,Br) 2) H₂O conc. H₂SO Compound C Heat A O Na B. Identify the major product of the reaction between 1-butanol and potassium tert-butoxide. C. Ot-Bu Product A: о о Identify the bases below that can be used to deprotonate a terminal alkyne. Select all that apply. Product B: BuLi NaOCH3 O NaH NaOH NINH, Explain your choices. ✓ The base(s) selected above is/are weaker than the acetylide base, thus favoring the forward reaction. The base(s) selected above is/are stronger than the acetylide base, thus favoring the reverse reaction. The base(s) selected above is/are weaker than the acetylide base, thus favoring the reverse reaction. The base(s) selected above is/are stronger than the acetylide base, thus favoring the forward reaction. о о th₂ B Pt F. 12.42a Draw the structure of compound 'A Draw Your Solution Propose an efficient synthesis for the following transformation: OH The transformation above can be performed with some reagent or combination of the reagents listed below. Give the necessary reagent(s) in the correct order, as a string of letters (without spaces or punctuation, such as "EBF"). If there is more than one correct solution, provide just one answer. A B C NaOEt t-BuOK PCC, CH2Cl2 D E F 1) MeMgBr 2) H3O Na2Cr2O7, H2SO4, H₂O conc. H2SO4, heat H I TsCl, py 1) BH-THF 2) H₂O₂, H₂O G Propose an efficient synthesis for the following transformation: The transformation above can be performed with some reagent or combination of the reagents listed below. Give the necessary reagent(s) in the correct order, as a string of letters (without spaces or punctuation, such as "EBF"). If there is more than one correct solution, provide just one answer. CAF A B C Mel H2, Lindlar's catalyst NaNH, D E F 1) MeMgBr 1)03 1) R₂BH 2) H₂O* 2) H₂O 2) H2O2, NaOH G 1) EtMgBr 2) H₂O* Н H₂O, H₂SO4, HgSO4 Na2Cr2O7, H₂SO4, H₂O
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