Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Identify the indicated faces in the molecules below as Re or Si.
![### Identifying Faces in Organic Molecules
**Objective:** Determine whether the indicated faces in the molecules are Re (Re-face) or Si (Si-face).
#### First Molecule:
- **Structure Description:** The molecule consists of a carbon atom doubly bonded to an oxygen atom, with groups attached as follows: `(CH3)2CH─`, `CH2N(CH3)2`.
- **Indicated Face:** A red arrow labeled "a" points upwards toward the carbon-oxygen double bond from the `(CH3)2CH─` group, while another arrow labeled "b" points downwards from the `CH2N(CH3)2` group.
#### Second Molecule:
- **Structure Description:** A bridged bicyclic system with a substituent containing two methyl (CH3) groups attached to a single carbon on the bridge.
- **Indicated Face:** A red arrow labeled "a" is pointing above the plane of the molecule, and another arrow labeled "b" is pointing below the plane at the carbon atom bonded to the methyl groups.
### Tasks:
For each molecule, identify:
- **Side a:** Use the given options to select whether this face is Re or Si.
- **Side b:** Use the given options to select whether this face is Re or Si.
Each face represents a different spatial orientation around the chiral center or double bond, important for understanding stereochemistry in organic chemistry.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fd20000fd-c8aa-4301-a2c7-8913bd047299%2F10da91e2-524d-4fab-9842-387aba2e7459%2F4hes8vl_processed.png&w=3840&q=75)
Transcribed Image Text:### Identifying Faces in Organic Molecules
**Objective:** Determine whether the indicated faces in the molecules are Re (Re-face) or Si (Si-face).
#### First Molecule:
- **Structure Description:** The molecule consists of a carbon atom doubly bonded to an oxygen atom, with groups attached as follows: `(CH3)2CH─`, `CH2N(CH3)2`.
- **Indicated Face:** A red arrow labeled "a" points upwards toward the carbon-oxygen double bond from the `(CH3)2CH─` group, while another arrow labeled "b" points downwards from the `CH2N(CH3)2` group.
#### Second Molecule:
- **Structure Description:** A bridged bicyclic system with a substituent containing two methyl (CH3) groups attached to a single carbon on the bridge.
- **Indicated Face:** A red arrow labeled "a" is pointing above the plane of the molecule, and another arrow labeled "b" is pointing below the plane at the carbon atom bonded to the methyl groups.
### Tasks:
For each molecule, identify:
- **Side a:** Use the given options to select whether this face is Re or Si.
- **Side b:** Use the given options to select whether this face is Re or Si.
Each face represents a different spatial orientation around the chiral center or double bond, important for understanding stereochemistry in organic chemistry.
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